Untitled

Troitskaya, L. L.; Demeshchik, T. V.; Sokolov, V. I.; Sciences, Radiation Research I. A. MamedyarovaDepartment of Azerbaijan Academy of; Malézieux, Bernard; Gruselle, Michel

doi:10.1023/a:1011377611293

Cited by 5 publications

(1 citation statement)

References 9 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Recently Veciana et al [45] have proposed the synthesis of a molecular ferromagnet starting from bis(hexafluoroacetylacetonate)manganese(II) coordonated by an optically active nitroxide radical. Others optically active 2D networks were synthesised using as starting materials Á or Ã [Cr(ox) 3 ] 3 À anionic bricks in the presence of Ni 2 þ or Mn 2 þ and of achiral ferrocenic ammonium salts [C 5 H 5 FeC 5 H 4 -CH 2 NR 3 ] þ with R ¼ n-ethyl to n-butyl [28,47]. The Circular dichroism (CD) curves for R ¼ n-propyl are shown in Figure 5.…”

Section: Cotton and Faraday Effectmentioning

confidence: 99%

Polyfunctional Two- (2D) and Three- (3D) Dimensional Oxalate Bridged Bimetallic Magnets

Cl�ment

Decurtins

Gruselle

et al. 2003

Monatshefte f�r Chemie / Chemical Monthly

View full text Add to dashboard Cite

We report major results concerning polyfunctional two-(2D) and three-(3D) dimensional oxalate bridged bimetallic magnets. As a consequence of their specific organisation they are composed of an anionic sub-lattice and a cationic counter-part. These bimetallic polymers can accommodate various counter-cations possessing specific physical properties in addition to the magnetic ones resulting from the interactions between the metallic ions in the anionic sub-lattice. Thus, molecular magnets possessing paramagnetic, conductive and optical properties are presented in this review.

show abstract

Section: Cotton and Faraday Effectmentioning

confidence: 99%

Polyfunctional Two- (2D) and Three- (3D) Dimensional Oxalate Bridged Bimetallic Magnets

Cl�ment

Decurtins

Gruselle

et al. 2003

Monatshefte f�r Chemie / Chemical Monthly

View full text Add to dashboard Cite

show abstract

Enantioselective Self‐Assembly of Bimetallic [Mn^II (Δ)‐Cr^III(C₂O₄)₃]⁻ and [Mn^II (Λ)‐Cr^III(C₂O₄)₃]⁻ Layered Anionic Networks Templated by the Optically Active (Rp)‐ and (Sp)‐[1‐CH₂N(n‐C₃H₇)₃‐2‐CH₃C₅H₃FeC₅H₅]⁺ Ions

Gruselle

Thouvenot

Malézieux

et al. 2004

Chemistry A European J

View full text Add to dashboard Cite

The ferrocenic ammonium (Rp)- and (Sp)-[1-CH2NR(3-)-2-CH3-C5H3Fe-C5H5] iodide salts with R=CH3, C2H5, n-C3H7, n-C4H9, were synthesized starting from the (Rp)- and (Sp)-[1-CH2N(CH3)2-2-CH3-C5H3Fe-C5H5] amines obtained in their optically active forms through asymmetric cyclopalladation of [C5H5Fe-C5H4CH2N(CH3)2]. 1H NMR studies of these planar chiral 1,2-disubstituted ferrocenic ammonium iodide salts in the presence of the (Delta)-(tris(tetrachlorobenzenediolato)phosphate(V) anion), [(Delta)-Trisphat] support the formation of specific diastereomeric ion pairs. Such intermolecular interactions can be related to the self-assembly of the two-dimensional optically active compounds [[(Sp)-1-CH2N(n-C3H7)3-2-CH3-C5H3Fe-C5H5][Mn (Delta)-Cr(C2O4)3]] and [[(Rp)-1-CH2N(n-C3H7)3-2-CH3-C5H3Fe-C5H5][Mn (Lambda)-Cr(C2O4)3]] starting from the resolved (Rp)- and (Sp)-[1-CH2N(n-C3H7)3-2-CH3-C5H3Fe-C5H5]+ ion associated to the racemic anionic building block rac-[Cr(C2O4)3]3- and Mn2+. Both enantiomeric forms of the networks behave as ferromagnets with a Curie temperature of 5.7 K.

show abstract

Polyfunctional Two- (2D) and Three- (3D) Dimensional Oxalate Bridged Bimetallic Magnets

Clément¹,

Decurtins²,

Gruselle³

et al. 2003

Molecular Magnets Recent Highlights

View full text Add to dashboard Cite

show abstract

Untitled

Cited by 5 publications

References 9 publications

Polyfunctional Two- (2D) and Three- (3D) Dimensional Oxalate Bridged Bimetallic Magnets

Polyfunctional Two- (2D) and Three- (3D) Dimensional Oxalate Bridged Bimetallic Magnets

Enantioselective Self‐Assembly of Bimetallic [Mn^II (Δ)‐Cr^III(C₂O₄)₃]⁻ and [Mn^II (Λ)‐Cr^III(C₂O₄)₃]⁻ Layered Anionic Networks Templated by the Optically Active (Rp)‐ and (Sp)‐[1‐CH₂N(n‐C₃H₇)₃‐2‐CH₃C₅H₃FeC₅H₅]⁺ Ions

Polyfunctional Two- (2D) and Three- (3D) Dimensional Oxalate Bridged Bimetallic Magnets

Contact Info

Product

Resources

About

Untitled

Cited by 5 publications

References 9 publications

Polyfunctional Two- (2D) and Three- (3D) Dimensional Oxalate Bridged Bimetallic Magnets

Polyfunctional Two- (2D) and Three- (3D) Dimensional Oxalate Bridged Bimetallic Magnets

Enantioselective Self‐Assembly of Bimetallic [MnII (Δ)‐CrIII(C2O4)3]− and [MnII (Λ)‐CrIII(C2O4)3]− Layered Anionic Networks Templated by the Optically Active (Rp)‐ and (Sp)‐[1‐CH2N(n‐C3H7)3‐2‐CH3C5H3FeC5H5]+ Ions

Polyfunctional Two- (2D) and Three- (3D) Dimensional Oxalate Bridged Bimetallic Magnets

Contact Info

Product

Resources

About

Enantioselective Self‐Assembly of Bimetallic [Mn^II (Δ)‐Cr^III(C₂O₄)₃]⁻ and [Mn^II (Λ)‐Cr^III(C₂O₄)₃]⁻ Layered Anionic Networks Templated by the Optically Active (Rp)‐ and (Sp)‐[1‐CH₂N(n‐C₃H₇)₃‐2‐CH₃C₅H₃FeC₅H₅]⁺ Ions