2-Hydroxy-6-[(<i>m</i>-tolyliminio)methyl]phenolate

Shuja, Shaukat; Ali, Saqib; Khalid, Nasir; Meetsma, Auke

doi:10.1107/s1600536807012561

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2013

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“…For a related structure and background to Schiff bases, see: Shuja et al (2007). For further structural aspects, see: Blagus & Kaitner (2011).…”

Section: Related Literaturementioning

confidence: 99%

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6-[(2,4-Dimethylanilino)methylidene]-2-hydroxycyclohexa-2,4-dienone

et al. 2013

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Key indicators: single-crystal X-ray study; T = 100 K; mean (C-C) = 0.002 Å; R factor = 0.043; wR factor = 0.123; data-to-parameter ratio = 10.6.In the title compound, C 15 H 15 NO 2 , the dihedral angle between the aromatic rings is 5.86 (6) , and an intramolecular N-HÁ Á ÁO hydrogen bond generates an S(6) motif, which helps to stabilize the enamine-keto tautomer. An intramolecular O-HÁ Á ÁO hydrogen bond also occurs. In the crystal, inversion dimers linked by pairs of O-HÁ Á ÁO hydrogen bonds generate

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“…For a related structure and background to Schiff bases, see: Shuja et al (2007). For further structural aspects, see: Blagus & Kaitner (2011).…”

Section: Related Literaturementioning

confidence: 99%

“…As part of our ongoing studies of Schiff bases (Shuja et al 2007), here we report the synthesis and structure of title compound, (I), (Fig. 1).…”

Section: S1 Commentmentioning

confidence: 99%