2-chlorobenzaldehyde thiocarbohydrazone: a novel reagent for liquid-liquid extractive spectrophotometric determination of copper(II) from environmental and real samples

Sadlapurkar, Ashwini V.; Barache, Umesh B.; Shaikh, Abdul Basit; Gaikwad, Shashikant H.; Lokhande, Tukaram N.

doi:10.1080/03067319.2021.1912333

Cited by 6 publications

(1 citation statement)

References 17 publications

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“…These compounds and their metal complexes show biological activities such as antimicrobial, antioxidant, anticancer, antiviral, antidiabetic, and hepatoprotective (5)(6)(7)(8)(9)(10)(11)(12)(13)(14)(15)(16)(17). In addition, there has been an increase in the use of thiocarbohydrazones as spectrophotometric reagents in metal determination in recent years (18)(19)(20).…”

Section: Introductionmentioning

confidence: 99%

Synthesis, Spectral Characterization, Crystal Structure, and Antioxidant Properties of novel Palladium(II) Complex from ONS Donor 1,5-bis(2-hydroxybenzylidene)thiocarbohydrazone

Kaya

2023

Journal of the Turkish Chemical Society Section A: Chemistry

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A new Pd(II) complex, [Pd(PPh3)(L)] (L = 1,5-bis(2-hydroxybenzylidene)thiocarbohydrazone, PPh3 = triphenylphosphine), was synthesized and characterized by FTIR, 1H NMR and UV-Vis spectroscopies and elemental analysis. The molecular structure of [Pd(PPh3)(L)] was confirmed by the single-crystal X-ray diffraction technique. Palladium ion has distorted square planar geometry according to X-ray diffraction studies. The free thiocarbohydrazone (L), potentially a pentadentate ONSNO donor, acted as a tridentate ONS donor. The antioxidant capacity of the free thiocarbohydrazone and Pd(II) complex was determined using the CUPRAC (cupric reducing antioxidant capacity) method. Also, the DPPH method was used to test the free radical scavenging activity of the free thiocarbohydrazone and Pd(II) complex. Antioxidant activity studies showed that free thiocarbohydrazone exhibited better activity than Pd(II) complex.

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Section: Introductionmentioning

confidence: 99%

Synthesis, Spectral Characterization, Crystal Structure, and Antioxidant Properties of novel Palladium(II) Complex from ONS Donor 1,5-bis(2-hydroxybenzylidene)thiocarbohydrazone

Kaya

2023

Journal of the Turkish Chemical Society Section A: Chemistry

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Application of 2-chlorobenzaldehyde thiocarbohydrazone as a chromogenic ligand for cadmium(II) detection and removal from water and food

Sadlapurkar,

Barache,

Shaikh

et al. 2024

Journal of Trace Elements and Minerals

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Investigation of spectroscopic, crystallographic, thermal and antioxidant properties of mononuclear dioxomolybdenum(VI) complexes derived from a new symmetric bisthiocarbohydrazone

Kaya

2022

Polyhedron

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2-chlorobenzaldehyde thiocarbohydrazone: a novel reagent for liquid-liquid extractive spectrophotometric determination of copper(II) from environmental and real samples

Cited by 6 publications

References 17 publications

Synthesis, Spectral Characterization, Crystal Structure, and Antioxidant Properties of novel Palladium(II) Complex from ONS Donor 1,5-bis(2-hydroxybenzylidene)thiocarbohydrazone

Synthesis, Spectral Characterization, Crystal Structure, and Antioxidant Properties of novel Palladium(II) Complex from ONS Donor 1,5-bis(2-hydroxybenzylidene)thiocarbohydrazone

Application of 2-chlorobenzaldehyde thiocarbohydrazone as a chromogenic ligand for cadmium(II) detection and removal from water and food

Investigation of spectroscopic, crystallographic, thermal and antioxidant properties of mononuclear dioxomolybdenum(VI) complexes derived from a new symmetric bisthiocarbohydrazone

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