The existing pulsed laser technologies
and devices are mainly in
the infrared spectral region below 3 μm so far. However, longer-wavelength
pulsed lasers operating in the deep mid-infrared region (3–20
μm) are desirable for atmosphere spectroscopy, remote sensing,
laser lidar, and free-space optical communications. Currently, the
lack of reliable optical switches is the main limitation for developing
pulsed lasers in the deep mid-infrared region. Here, we demonstrate
that topological semimetal antimonene possesses an ultrabroadband
optical switch characteristic covering from 2 μm to beyond 10
μm. Especially, the topological semimetal antimonene shows a
very low saturable energy fluence (only 3–15 nJ cm–2 beyond 3 μm) and an ultrafast recovery time of ps level. We
also demonstrate stable Q-switching in fiber lasers at 2 and 3.5 μm
by using topological semimetal antimonene as passive optical switches.
Combined with the high environmental stability and easy fabrication,
topological semimetal antimonene offers a promising optical switch
that extends pulsed lasers into deep mid-infrared region.