2,6-Xylidinium nitrate

Abstract

Key indicators: single-crystal X-ray study; T = 293 K; mean (C-C) = 0.003 Å; R factor = 0.037; wR factor = 0.112; data-to-parameter ratio = 12.9.The structure of the title organic-inorganic hybrid material, C 8 H 12 N + ÁNO 3 À , results mainly from electrostatic interactions and bifurcated N-HÁ Á ÁO and C-HÁ Á ÁO hydrogen bonds. Organic 2,6-xylidinium cations and inorganic nitrate anions interact to form a three-dimensional hydrogen-bond network.

5-Chloro-2-methoxyanilinium nitrate

“…The torsion angle (t3) value indicates that the methoxy group lies out the plane of the benzene ring. This conformation resembles that observed in other compounds (Abid et al 2007, Aloui et al 2002, Hemissi et al 2005.…”

“…For related literature, see: Abid et al (2007); Aloui et al (2002); Desiraju & Steiner (1999); Hemissi et al (2005); Jayaraman et al (2002); Ouslati & Ben Nasr (2006); Steiner (2002); Kefi et al (2007).…”

Crystalline and Molecular Structure of Hydrated 2,6‐Xylidinium Tetrachlorozincate(II)

“…An examination of the organic moiety geometrical features shows that, the carbon atoms building the two phenyl rings of the title compound have a good coplanarity and they form a conjugated planes with average deviation of 0.025 and 0.037 Å, and they form between them a dihedral angle of 7.32°. The two crystallography independent 2,6-xilidinium cations involved in this crystal packing, exhibit C-C and C-N distances and C-C-C and C-C-N angles in the range usually found for this molecule [24][25] .…”