[2,6-Bis(2-pyrimidinylthiomethyl)pyridine]dichlorocopper(II) methanol solvate

Abstract

Lists of structure factors, anisotropic displacement parameters, H-atom coordinates and complete geometry have been deposited with the IUCr (Reference: SH1090). Copies may be obtained through The Managing Editor,

Ruthenium(II) Complexes with NS2 Pyridine-Based Dithia-Containing Ligands. Proposed Possible Structural Isomers and X-ray Confirmation of Their Existence

“…2-8 This type of ligands can be produced by a central pyridine ring bonded to two thioether-containing arms. This coordinating unit is responsible for the formation of complexes with different metals, principally with Cu, Ni, Pd, and Pt 7 and to much less extent with Fe . We have recently shown the singular coordinating ability of NS 2 ( S -aryl) ligands incorporating the moiety 2,6-bis(thiomethyl)pyridine.…”

Synthesis and Reactivity of Nickel(II) Complexes of the Pyridine-Based Phosphorus-Containing Macrocycle 6-Phenyl-15-aza-6-phospha-3,9- dithiabicyclo[9,3,1]pentadeca-1(15),11,13-triene

“…In the last years we have reported the synthesis and complexing behavior of several macrocyclic and open-chain ligands containing the NS 2 donor group which is present in the 2,6-bis(thiomethyl)pyridine unit. , In these papers we have demonstrated that some of the studied NS 2 -based macrocycles behave as neutral carriers in all-solid-state ion-selective electrodes discriminating Cu(II) from Ni(II) and Co(II) 1d. These results encouraged us to study the coordinating abilities of new macrocycles containing the 2,6-bis(thiomethyl)pyridine unit, and we have recently reported the synthesis of the phosphine containing macrocycle 6-phenyl-15-aza-6-phospha-3,9-dithiabicyclo[9,3,1]pentadeca-1(15),11,13-triene (L in Scheme ) .…”