2009
DOI: 10.1039/b821683e
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2,5-Dimethyl-2,4-hexadiene induced photodechlorination of 9,10-dichloroanthracene

Abstract: Photochemical formation of 9-chloroanthracene (MCA) from 9,10-dichloroanthracene (DCA) is observed in the presence of 2,5-dimethyl-2,4-hexadiene (DMH) in acetonitrile (AN). The mechanism of the reaction was investigated using kinetics, deuterium labeling, and quenching techniques. Contrary to conclusions in a recent publication, our work supports the salient features of the mechanism we had proposed earlier. DCA is photostable in degassed AN in the absence of DMH. When DMH is added, irradiation of DCA at 365 o… Show more

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Cited by 3 publications
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