{2,4-Dichloro-6-[2-(dimethylamino)ethyliminomethyl]phenolato}thiocyanatonickel(II)

Abstract

Key indicatorsSingle-crystal X-ray study T = 291 K Mean (C-C) = 0.005 Å Disorder in main residue R factor = 0.041 wR factor = 0.099 Data-to-parameter ratio = 16.1 For details of how these key indicators were automatically derived from the article, see View of the molecular structure of (I), showing the atom-labeling scheme. Displacement ellipsoids are drawn at the 30% probability level.

Azido{2-bromo-4-chloro-6-[2-(diethylamino)ethyliminomethyl]phenolato}nickel(II)

“…1). The bond lengths and angles (Table 1) subtended at atom Ni1 are within normal ranges and are comparable with the corresponding values observed in other similar nickel(II) complexes (Zhu et al, 2004;Wang, 2006;Wang & Wei, 2006;Liu et al, 2006;Zhang, 2006). No hydrogen-bonding interactions are observed in the crystal structure.…”

Bis{2-methoxy-6-[3-(methylamino)propyliminomethyl]phenolato}nickel(II)

“…The Ni atom, lying on the inversion centre, is six-coordinated by two phenolic oxygen atoms, two imine N atoms and two amine N atoms from two Schiff base ligands, forming an octahedral coordination geometry. The coordinative bond lengths and angles are within normal ranges and comparable with those observed in similar nickel(II) complexes (Zhu et al, 2004;Liu et al, 2006;Zhang, 2006;Diao, 2007;Diao, Li et al, 2007).…”

“…For related crystal structures, see: Zhu et al (2004); Liu et al (2006); Zhang (2006); Tang (2006); Diao (2007); Diao et al (2007).…”

Diaquabis{2,4-dibromo-6-[2-(isopropylammonio)ethyliminomethyl]phenolato}nickel(II) dichloride hemihydrate

“…For related literature, see: Angulo et al (2001); Dey et al (2004); Diao (2007); Diao et al (2007); Edison et al (2004); Liu et al (2006); Ramadevi et al (2005); Suh et al (1996); Tang (2006); Zhang (2006); Zhu et al (2004).…”