2013
DOI: 10.1107/s1600536813029693
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(2-{[4-(Chloridomercuryl)phenyl]iminomethyl}pyridine-κ2N,N′)diiodidomercury(II) dimethyl sulfoxide monosolvate

Abstract: The title dimethyl sulfoxide solvate, [Hg2(C12H9ClN2)I2]·C2H6OS, features tetra­hedrally and linearly coordinated HgII atoms. The distorted tetrahedral coordination sphere is defined by chelating N atoms that define an acute angle [69.6 (3)°] and two I atoms that form a wide angle [142.80 (4)°]. The linearly coordinated HgII atom [177.0 (4)°] exists with a donor set defined by C and Cl atoms. Secondary inter­actions are apparent in the crystal packing with the tetra­hedrally and linearly coordinated HgII atoms… Show more

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