2,3-Bisphosphonosuccinic Acid Hexamethyl Ester [(CH3O)2(O)P-CH-COOCH3]2– NMR-Spectroscopic Studies of ABX and [AM3R3X]2+Z6Spin Systems

Hägele, Gerhard; Dettmann, Joachim; Huben, Krzysztof; Jankowski, Stefan; Bálint, Erika; Keglevich, György

doi:10.1080/10426507.2013.858255

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Reactions Taking Place More Efficiently Under Mw Conditions1

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“…MW addition was useful to enhance the addition of dialkyl phosphites, ethyl phenyl‐ H ‐phosphinate and diphenylphosphine oxide to the more reactive double‐bond of N ‐phenyl and N ‐methylmaleimide, as well as maleic anhydride . The addition of two equivalents of >P(O)H species to dimethyl acetylenedicarboxylate and analogous derivatives was also studied …”

Section: Reactions Taking Place More Efficiently Under Mw Conditionsmentioning

confidence: 99%

The Impact of Microwaves on Organophosphorus Chemistry

Keglevich

2018

The Chemical Record

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A personal account on the pioneering results on microwave (MW)-assisted organophosphorus syntheses obtained in the last decade is presented. The broad spectrum of the reactions studied exemplifies the advantages of the MW technique as a green tool regarding efficiency and the simplification of catalyst systems. Theoretical calculations for a few typical models helped us to explore the scope and limitations of the application of MW irradiation.

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Section: Reactions Taking Place More Efficiently Under Mw Conditionsmentioning

confidence: 99%