Using B3LYP/6-311+G* and other methods, twist angles and torsional energies were obtained for biphenyl (BP), 2-halogen BPs, 2,2′-dihalogen BPs, and 3,3′-dihalogen BPs, the halogens ranging from F to I. The results were compared with available gas phase and X-ray data. 2,2′-difluoro BP has a rotational double minimum, at 57.9 and 128.9°, whereas the other 2,2′-dihalogen BPs have a single minimum at dihedral angles ranging from 84.9 to 94.8°. All 3,3′-dihalogen BPs have a double minimum at about 45 and 135°. Optimized twist angles and energy barriers were also calculated for 2,2′-dimethyl BP and for perfluoro as well as perchloro BP. Most structures are accounted for by steric effects. For 2,2′-dihalogen BPs, however, attractive forces also appear to play a role, as evidenced by the dihedral angle of 2,2′-dichloro BP lying well below 90°.