The title compound, C28H28N2O2, was synthesized by condensation of 1-naphthaldehyde with 1,6-bis(aminooxy)hexane in ethanol. The molecule is disposed about a crystallographic centre of symmetry. In the crystal structure, molecules are linked through strong intermolecular π–π stacking interactions [interplana distance = 2.986 (2) Å], forming a three-dimensional network.