1999
DOI: 10.1107/s0108270198018095
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(2,2'-Bipyridine-N,N')(7-oxabicyclo[2.2.1]heptane-2-exo,3-exo-dicarboxylato-κ3O2,3,7)manganese(II)–7-oxabicyclo[2.2.1]heptane-2-exo,3-exo-dicarboxylic acid–water (1/1/1)

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“…Monodentate binding of cantharidinate in metal complexes has not been documented in the literature so far [26]. As a rule, the cantharidinate anion acts as a tridentate ligand chelating through the ether and two carboxylate O-atoms [27] or as a bridging ligand in infinite polymeric structures [28] [29]. The bridging ether O-atom of the cantharidinate molecule is not involved in coordination to the platinum ion in (1,2-diaminopropane)platinum(II) cantharidinate [30].…”
mentioning
confidence: 99%
“…Monodentate binding of cantharidinate in metal complexes has not been documented in the literature so far [26]. As a rule, the cantharidinate anion acts as a tridentate ligand chelating through the ether and two carboxylate O-atoms [27] or as a bridging ligand in infinite polymeric structures [28] [29]. The bridging ether O-atom of the cantharidinate molecule is not involved in coordination to the platinum ion in (1,2-diaminopropane)platinum(II) cantharidinate [30].…”
mentioning
confidence: 99%