1D helical silver(I)-based coordination polymer containing pyridyl diimide ligand for Fe(III) ions detection

1D and 2D Silver-Based Coordination Polymers with Thiomorpholine-4-carbonitrile and Aromatic Polyoxoacids as Coligands: Structure, Photocatalysis, Photoluminescence, and TD-DFT Study

“…A wide variety of functional properties make Ag-CPs useful for different applications. These properties include antibacterial activity, , gas sensing, proton conductivity, high capacitance and good cycling ability, , and chemical sensing. , Moreover, Ag-CPs might play a significant role in environmental remediation, − as they have been tailored to achieve a particular mechanism of oxoanion exchange to maximize their effectiveness . Most recently, there have been several reports on Ag-CPs manifesting excellent catalytic and photocatalytic properties. − Environmentally friendly and recyclable Ag-CP with 9,10-anthraquinone-1,4-dicarboxylate acid catalyzed the reaction of the visible-light-driven aerobic oxidation of alkynes into 1,2-diketones under ambient conditions .…”

“…Luminescent CPs are of great interest, since they have been employed in sensing (metal ions, solvents, and explosives) and (bio)­imaging. − Some of the investigated Ag-CPs showed potential for ion ,,, and solvent sensing. In that sense, the goal of our work is the preparation of novel Ag-CPs, the characterization of their luminescent properties at both low and room temperature, and an explanation of their origin using TD-DFT.…”

“…L was chosen as a ligand since it belongs to the class of bis-monodentate ligands which are able to form Ag-CPs, − although it has never been used for this purpose. On the other hand, selected coligands showed photoluminescent properties − and can easily form Ag-CPs ,,,,− photoluminescent in some cases. − ,, …”

“…These properties include antibacterial activity, 47,53 gas sensing, 49 proton conductivity, high capacitance and good cycling ability, 54,55 and chemical sensing. 19,56 Moreover, Ag-CPs might play a significant role in environmental remediation, 57−59 as they have been tailored to achieve a particular mechanism of oxoanion exchange to maximize their effectiveness. 60 Most recently, there have been several reports on Ag-CPs manifesting excellent catalytic and photocatalytic properties.…”

Metallosupramolecular Architectures of Ambivergent Bis(Amino Acid) Biphenyldiimides

“…In terms of coordination chemistry,aBPDI-based ligand has only been reported twice previously,a sb is(methylpyridyl) derivatives, in ac oordination polymers in whicht he ligand can be seen to adopt either a "U" or an "S" shaped conformation due to its flexibility. [10] Other carboxylate ligands based on the versatile diimidec ore have also been reported derived from either amino acids [11] or benzoate/isophthalate groups. [12] Herein we report the synthesis and study of two enantiopure ligandsb ased on the biphenyldiimide core group and efforts to replicate catenane and rotaxane motifs that were previously observed with the relatedN DI species.…”