188. Some complexes of tertiary phosphines with ruthenium(II) and osmium(II)

Chatt, J.; Hayter, R. G.

doi:10.1039/jr9610000896

Cited by 161 publications

(83 citation statements)

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“…Synthesis of Platinum Metallopolyynes P0-P3: The polymers were prepared by the dehydrohalogenative polycondensation between trans-[PtCl 2 (PBu 3 ) 2 ] [24] and each of L0-L3 under very similar conditions. A typical procedure was given for P1 starting from L1.…”

Section: Methodsmentioning

confidence: 99%

Effect of Oligothienyl Chain Length on Tuning the Solar Cell Performance in Fluorene‐Based Polyplatinynes

Liu

Wong

et al. 2008

Adv Funct Materials

127

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A series of solution‐processable and strongly visible‐light absorbing polyplatinynes containing oligothienyl–fluorene ring hybrids were synthesized and characterized. These rigid‐rod organometallic materials are soluble in polar organic solvents and show intense absorptions in the visible spectral region, rendering them excellent candidates for bulk heterojunction polymer solar cells. The photovoltaic behavior depends significantly on the number of thienyl rings along the polymer chain, and some of these polymer solar cells show high power conversion efficiencies (PCEs) of up to 2.9% and a peak external quantum efficiency to 83% under AM1.5 simulated solar illumination. The effect of oligothienyl chain length on improving the polymer solar cell efficiency and on their optical and charge transport properties is elucidated in detail. At the same blend ratio of 1:5, the light‐harvesting capability and PCE increase markedly with increasing number of thienyl rings. The power dependencies of the solar cell parameters (including the short‐circuit current density, open‐circuit voltage, fill‐factor, and PCE) were also examined. The present work opens up an attractive avenue to developing conjugated metallopolymers with broad and strong solar energy absorptions and tunable solar cell efficiency and supports the potential of metalated conjugated polymers for efficient power generation.

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Section: Methodsmentioning

confidence: 99%

Effect of Oligothienyl Chain Length on Tuning the Solar Cell Performance in Fluorene‐Based Polyplatinynes

Liu

Wong

et al. 2008

Adv Funct Materials

127

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“…Compounds trans-[PtPh(Cl)(PEt 3 ) 2 ] [28] and trans-[Pt(PBu 3 ) 2 Cl 2 ] [29] were prepared according to methods described in the literature. The characterization of products was achieved using the following instruments: Nicolet 550 FTIR, Varian 400 MHz NMR, Finnigan MAT SSQ710 and HP 8453 UV/VIS spectrometers.…”

Section: General Methodsmentioning

confidence: 99%

Synthesis, Redox and Optical Properties of Low-Bandgap Platinum(II) Polyynes with 9-Dicyanomethylene-Substituted Fluorene Acceptors

Wong

Choi

et al. 2001

Macromol. Rapid Commun.

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In view of the strong electron‐withdrawing nature of the cyano substituent, a blue donor/acceptor‐type organometallic polymer (trans‐[—Pt(PBu3)2—C≡C—R—C≡C—]n (R = 9‐dicyanomethylenefluorene‐2,7‐diyl)) was prepared in good yield by CuI‐catalyzed polymerization involving the dehydrohalogenating coupling of trans‐[Pt(PBu3)2Cl2] and H—C≡C—R—C≡C—H. The thermal, redox and photoconducting properties of the polymer are reported. Electronic absorption studies indicate that it has a bandgap of 1.58 eV which is the lowest among any of the metal polyyne polymers reported in the literature. The derivatization of the polymer backbone with electron deficient dicyano‐substituted electron acceptor in the side chain is found to be effective to tune the bandgap of this class of materials while maintaining their solubility and processability.

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“…During an investigation of the reactivity of cationic hydrazine complexes of Ru (Hough & Singleton, 1972 (Ashworth & Singleton, 1975;Chatt & Hayter, 1961;Chatt, Shaw & [Ru2CIs(PMe2Ph)6]PF6 Field, 1964;Head & Nixon, 1975). A structure determination was undertaken to confirm the chemical deductions and to compare the structure with that of the trihydroxo analogue (Ashworth, Nolte & Singleton, 1975).…”

mentioning

confidence: 99%

Tri-μ-chloro-hexakis(dimethylphenylphosphine)diruthenium(II) hexafluorophosphate

Laing¹,

Pope²

1976

Acta Crystallogr Sect B

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Abstract. [Ru2C13(PMe2Ph)6]PF6, Ru2ClaPTF6C48H66, M=1282. Monoclinic, P21/c, a=14.43 (1), b=16.41 (1), c=23-86 (2)A, fl=97.5 (1) °, V=5601 A 3, Dm= 1"55 (1), Dc=1"53 g cm -3, Z=4, /z=9"25 cm -1. R= 0.069 for 4983 observed data; two Ru, seven P and three C1 atoms anisotropic. The Ru atoms are approximately octahedrally coordinated: Ru...Ru= 3.39, Ru-C1 range from 2.46 to 2.52, Ru-P from 2.28 to 2.30 A; average Ru-CI-Ru = 86 °.

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188. Some complexes of tertiary phosphines with ruthenium(II) and osmium(II)

Cited by 161 publications

References 0 publications

Effect of Oligothienyl Chain Length on Tuning the Solar Cell Performance in Fluorene‐Based Polyplatinynes

Effect of Oligothienyl Chain Length on Tuning the Solar Cell Performance in Fluorene‐Based Polyplatinynes

Synthesis, Redox and Optical Properties of Low-Bandgap Platinum(II) Polyynes with 9-Dicyanomethylene-Substituted Fluorene Acceptors

Tri-μ-chloro-hexakis(dimethylphenylphosphine)diruthenium(II) hexafluorophosphate

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