182. Liquid-phase reactions at high pressures. Part I. Hydrolysis of esters, and the Knoevenagel reaction

Newitt, D. M.; Linstead, R. P.; Sapiro, Rossana; Boorman, E. J.; Bone, William A.; Thorpe, Jocelyn Field

doi:10.1039/jr9370000876

Search citation statements

Order By: Relevance

Paper Sections

Select...

The Displacement Of Equilibria In Heterogeneous Systems1

Citation Types

Supporting

Mentioning

Contrasting

Year Published

1941

2011

Publication Types

Select...

Book3

Article2

Other1

Relationship

Self Cite0

Independent6

Authors

Journals

Cited by 15 publications

(1 citation statement)

References 0 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…During the last decade quite a number of examples of the effect of pressure on reaction velocities in condensed systems have been studied, especially by workers at the Imperial Chemical Industries Laboratory (16, 27, 33) and at Imperial College, London (26), and I regret that Professor Linstead could not be present to discuss the results of some of these investigations. In condensed systems pressure changes may produce large changes in reaction velocity, including the special case of reactions which do not go at atmospheric pressure, proceeding at finite rates under high pressures.…”

Section: The Displacement Of Equilibria In Heterogeneous Systemsmentioning

confidence: 99%

Introduction to the Symposium.

Gibson¹

1941

Chem. Rev.

View full text Add to dashboard Cite

Section: The Displacement Of Equilibria In Heterogeneous Systemsmentioning

confidence: 99%

Introduction to the Symposium.

Gibson¹

1941

Chem. Rev.

View full text Add to dashboard Cite

TheKnoevenagel Condensation

Jones

2011

Organic Reactions

View full text Add to dashboard Cite

Knoevenagel's first papers in this field were concerned with the condensation of formaldehyde with diethyl malonate and with ethyl benzoylacetate. The catalyst was ethylamine. A number of other aldehydes were reported to condense similarly with diethyl malonate, ethyl benzoylacetate, ethyl benzoylpyruvate, and acetylacetone under the influence of various primary and secondary amines. In 1896, Knoevenagel reported benzaldehyde with ethyl aceoacetate condensed at room temperature in the presence of piperdine to give a bis compound, but that when the reaction was run in a freezing mixture, the product was acetoacetate. For the purposes of this chapter, the Knoevenagel condensation is defined as the reaction between an aldehyde or ketone or any compound having an active methylene group, brought about by an organic base or ammonia and their salts.

show abstract

Pure Liquids: Extended References

Wohlfarth¹,

Wohlfarth²

Refractive Indices of Inorganic, Organometallic, and Organononmetallic Liquids, and Binary Liquid Mixtures

View full text Add to dashboard Cite

182. Liquid-phase reactions at high pressures. Part I. Hydrolysis of esters, and the Knoevenagel reaction

Cited by 15 publications

References 0 publications

Introduction to the Symposium.

Introduction to the Symposium.

TheKnoevenagel Condensation

Pure Liquids: Extended References

Contact Info

Product

Resources

About