Abstract:Evidence is presented in support of the view that the rearrangerncnt of N-chloroacetanilide in the fused state is an intermolecular chlorination.IT is known that N-chloroacetanilide changes above its melting point into a mixture of 0-and P-chloroacetanilide ; other N-chloroacylarylamides behave simi1arly.l" Therc arc already sufficient observations to exclude belief that this migration is a true intramolecular rearrangement, if the term is used in the strict sense of implying that the chlorine remains within t… Show more
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