The reaction of 2‐N‐(acetylanilino)‐3‐chloro‐1,4‐naphthoquinone (2) with bifunctional aromatic amines afforded angular heterocycles 6 and 7. Reductive acetylation of 7 provided o‐acyl 9 and O,N‐diacyl 10 derivatives depending upon the reaction conditions. The ir, uv, pmr and mass spectral data are also presented.