Abstract. In this study, we introduce new observations of sea–air fluxes of carbon
dioxide using the eddy covariance method. The measurements took place at the
Utö Atmospheric and Marine Research Station on the island of Utö in the
Baltic Sea in July–October 2017. The flux measurement system is based on a
closed-path infrared gas analyzer (LI-7000, LI-COR) requiring only occasional
maintenance, making the station capable of continuous monitoring. However,
such infrared gas analyzers are prone to significant water vapor interference
in a marine environment, where CO2 fluxes are small. Two LI-7000 analyzers were run in parallel to test the effect of a sample air
drier which dampens water vapor fluctuations and a virtual impactor,
included to remove liquid sea spray, both of which were attached to the
sample air tubing of one of the analyzers. The systems showed closely similar
(R2=0.99) sea–air CO2 fluxes when the latent heat flux was low, which
proved that neither the drier nor the virtual impactor perturbed the CO2
flux measurement. However, the undried measurement had a positive bias that
increased with increasing latent heat flux, suggesting water vapor
interference. For both systems, cospectral densities between vertical wind speed and CO2
molar fraction were distributed within the expected frequency range, with a
moderate attenuation of high-frequency fluctuations. While the setup equipped
with a drier and a virtual impactor generated a slightly higher flux loss, we
opt for this alternative for its reduced water vapor cross-sensitivity and
better protection against sea spray. The integral turbulence characteristics
were found to agree with the universal stability dependence observed over
land. Nonstationary conditions caused unphysical results, which resulted in
a high percentage (65 %) of discarded measurements. After removing the
nonstationary cases, the direction of the sea–air CO2 fluxes was in good
accordance with independently measured CO2 partial pressure difference
between the sea and the atmosphere. Atmospheric CO2 concentration changes
larger than 2 ppm during a 30 min averaging period were found
to be associated with the nonstationarity of CO2 fluxes.