2015
DOI: 10.5935/0103-5053.20150223
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Electrosynthesis and Characterisation of Polymer Nanowires from Thiophene and its Oligomers

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Cited by 3 publications
(4 citation statements)
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“…PPy bulk presents a p-doping/undoping current density negligible compared to that of PPy-nw. This behavior is consistent with the significant increase in effective area attributable to the nanostructuring of the deposit on the same support area, similar to outcomes from different polymers in past reports [4,22,26,[36][37][38][39][40][41].…”
Section: Resultssupporting
confidence: 91%
“…PPy bulk presents a p-doping/undoping current density negligible compared to that of PPy-nw. This behavior is consistent with the significant increase in effective area attributable to the nanostructuring of the deposit on the same support area, similar to outcomes from different polymers in past reports [4,22,26,[36][37][38][39][40][41].…”
Section: Resultssupporting
confidence: 91%
“…The mesoporosity is then revealed by the removal of surfactant molecules from the film. Such oriented mesoporous silica films on electrodes have proven to be of interest for electrochemical sensing , and biosensing, ,, electrochemiluminescence, , energy, polymer nanowire growth, ,, and separation/permselective membranes. ,, Moreover, the EASA approach developed in our group is applicable to the generation of functionalized thin films in one step by self-assembly co-condensation using organosilane reagents, including a method applicable to any kind of organofunctional groups via click chemistry for mono- or multi-functionalized materials . Such modified thin films extend the scope of application of oriented mesostructures by opening new avenues in the fields of sensing, electrocatalysis, ,, fluorescence, and molecular electronics…”
Section: Introductionmentioning
confidence: 99%
“…Several reports are dealing with the synthesis of conducting polymers by electropolymerization using vertically oriented silica nanochannels as a template, notably for polypyrrole (PPy) [354,355], polythiophene [356,357] or poly(3,4-ethylenedioxythiophene) (PEDOT) [358,359], polyaniline (PANI) [352,360] and polyquinone [361,362]. Sometimes the silica membrane is deposited onto a preformed layer of bulk polymer prior to nanowires growth in order to ensure a good adhesion of these latter onto the electrode support [355,359,362].…”
Section: Growth Of Nanofilaments Through the Mesopore Channelsmentioning
confidence: 99%
“…However, the observed diameters are mostly much larger (10-30 nm [355,356,363]) than the aperture of the silica nanochannels (2-3 nm), suggesting a growth outside the membrane, even if thinner deposits (ca. 3-5 nm size) are reported in some cases [352,357,360]. Of related interest is the electrogeneration of Prussian Blue nanowires, exhibiting an electrochemical behavior suggesting very small size but without direct evidence of the nanofilaments in the nanochannels [364].…”
Section: Growth Of Nanofilaments Through the Mesopore Channelsmentioning
confidence: 99%