2015
DOI: 10.5935/0103-5053.20150041
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Kinetics and Product Analysis of the Electrochemical Dehalogenation of Hexachlorobenzene

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“…It is well-known that the more halogens in an aromatic structure, the more toxic it is. , Therefore, the removal of halogen atoms is a viable strategy. Interestingly, electrochemical halogen removal can be performed stepwise. A dechlorination example using a conducting polymer involves Pd 0 nanoparticles immobilized in a PPy matrix as described above for the reductive dechlorination of harmful 3,3′,4,4′-tetrachlorobiphenyl in the presence of hydrogen. The removal of chlorine atoms leads ultimately to biphenyl, therefore reducing toxicity …”
Section: Part 1 Applications That Take Advantage Of the Tridimensiona...mentioning
confidence: 99%
“…It is well-known that the more halogens in an aromatic structure, the more toxic it is. , Therefore, the removal of halogen atoms is a viable strategy. Interestingly, electrochemical halogen removal can be performed stepwise. A dechlorination example using a conducting polymer involves Pd 0 nanoparticles immobilized in a PPy matrix as described above for the reductive dechlorination of harmful 3,3′,4,4′-tetrachlorobiphenyl in the presence of hydrogen. The removal of chlorine atoms leads ultimately to biphenyl, therefore reducing toxicity …”
Section: Part 1 Applications That Take Advantage Of the Tridimensiona...mentioning
confidence: 99%