Abstract:Complexos do tipo [RuCl 2 (PPh 3 ) 2 (amina) x ], com NH 2 Ph (1; x = 2), NH 2 Bz (2; x = 2) and NHBuPh (3; x = 1) na presença de etildiazoacetato (EDA), foram aplicados em reações de polimerização via metátese por abertura de anel (ROMP) de norborneno (NBE), norbornadieno (NBD) e diciclopentadieno (DCPD). Rendimentos quantitativos de poliNBE foram obtidos a 50 °C por 30 min usando 1 e por 5 min usando 2. Isso ocorreu a 25 °C por 5 min quando foi usado 3. Os valores do índice de polidispersidade ( ). O complex… Show more
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