2016
DOI: 10.5935/0100-4042.20160062
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Calculation of Conditional Equilibrium in Serial Multiple Precipitation of Metal Sulfides With Hydrogen Sulfide Stream Generated From Sodium Sulfide: A Didactic Tool for Chemistry Teaching

Abstract: Recebido em 16/11/2015; aceito em 22/01/2016; publicado na web em 12/04/2016Hydrogen sulfide is presented in textbooks as toxic, environmentally unacceptable species, however some positive effects in human metabolism were discovered in the last decades. It is important to offer students also some new information about this compound. As didactic tool in this case may serve serial precipitation of Cd , Mn 2+ and Pb 2+ ions forming various colored sulfides in bubblers with chemically generated hydrogen sulfide s… Show more

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“…In Timm's method, exogenous sulphide competes for metals with a mixture of endogenous ligands 16,17,[122][123][124][125][126] . Different free metal fractions may be selected by changing the concentration of sulphide ions 127,128 , or the duration of sulphide treatment 53 . This may explain differences in staining pattern between the following three versions of Timm's method.…”
Section: Technical Validationmentioning
confidence: 99%
“…In Timm's method, exogenous sulphide competes for metals with a mixture of endogenous ligands 16,17,[122][123][124][125][126] . Different free metal fractions may be selected by changing the concentration of sulphide ions 127,128 , or the duration of sulphide treatment 53 . This may explain differences in staining pattern between the following three versions of Timm's method.…”
Section: Technical Validationmentioning
confidence: 99%