In an attempt to add ligands to the sixth (axial) position of vanadyl bis-acetylacetonate: A unique tetranuclear vanadyl species
Roger Lalancette,
Ivan Bernal
Abstract:We have explored the interaction of [(acac)2V=O] (acac = acetylacetone) with a series of potential ligands which were chosen because of their expected ability to attach themselves onto its sixth (axial) position. Furthermore, some of the species chosen were expected to have the capability of linking pairs of [(acac)2V=O] molecules, thus creating magnetically coupled substances whose behavior would be interesting to document by magnetic as well as structural methods. Some of the synthetic results were surprisin… Show more
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