“…1B). 24 Meanwhile, the HOMO of the CO molecule is energetically closer to the metal d-orbital than that of the N 2 molecule, resulting in a more stable metal-CO s bond. As a result, N 2 is usually a poorer p-acceptor ligand than CO, 25 while achieving horizontal N 2 adsorption is even more challenging.…”
Electrocatalytic urea synthesis under mild conditions via the nitrogen (N2) and carbon monoxide (CO) coupling represents an ideal and green alternative to energy-intensive traditional synthetic protocol. However, this process is...
“…1B). 24 Meanwhile, the HOMO of the CO molecule is energetically closer to the metal d-orbital than that of the N 2 molecule, resulting in a more stable metal-CO s bond. As a result, N 2 is usually a poorer p-acceptor ligand than CO, 25 while achieving horizontal N 2 adsorption is even more challenging.…”
Electrocatalytic urea synthesis under mild conditions via the nitrogen (N2) and carbon monoxide (CO) coupling represents an ideal and green alternative to energy-intensive traditional synthetic protocol. However, this process is...
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