Simultaneous preconcentration of lead and cadmium ions with methyltrioctylammonium chloride supported on microcrystalline naphthalene and determination by flame atomic absorption spectrometry

Abstract

A sensitive and selective preconcentration method has been developed for the determination of trace amounts of lead and cadmium ions by using naphthalenemethyltrioctylammonium chloride as an adsorbent. Lead and cadmium ions were retained by the adsorbent in the minicolumn as PbI4 2-and CdI4 2-, respectively. The column was washed by 5 mL of 2 mol L -1 nitric acid solution to elute the adsorbed cations. The collected eluents then were determined by flame atomic absorption spectrometry (FAAS). Potential factors affecting on the recovery of the analytes were investigated. Meanwhile optimum conditions were established. The preconcentration factor for lead (II) and cadmium (II) have been 300 and 100, respectively. The calibration curves were linear in the range of 3 to 100 ng mL -1 for Pb 2+ and in the range of 1 to 100 ng mL -1 for Cd 2+ , in the original water samples. The detection limits for Pb 2+ and Cd 2+ are 0.42 and 0.072 ng mL -1 respectively. On the other hand, the relative standard deviation (RSD) for 11 replicate measurements of 20 ng mL -1 Pb 2+ and Cd 2+ were 2.2% and 1.4% in the initial solution respectively (n=11). The developed method was successfully applied for the determination of trace Pb 2+ and Cd 2+ ions in a variety of water samples. Cadmium Lead FAAS Preconcentration Microcrystalline naphthalene

Normal and second derivative spectrophotometric determination of niobium using solid phase extraction technique

“…Solid phase extraction with micro crystalline naphthalene has recently received great attention. The advantages of this method are simple procedure, rapid phase separation, high extraction capacity and easy combination with various highly sen sitive instrumental techniques [20].…”