Properties of Cu-Co Composite Catalysts for Synthesis of Aliphatic Alcohols

Куликова, М. В.; Chudakova, M. V.; Иванцов, М. И.; Kuz’min, Alexei E.; Krylova, A. Yu.; Максимов, А. Л.

doi:10.21577/0103-5053.20200179

Cited by 3 publications

(2 citation statements)

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“…1 (b)). Such an effect was recorded in the presence of catalysts based on carbonized cellulose obtained by the organic matrix method under the conditions of carbon monoxide hydrogenation [10].…”

Section: Resultsmentioning

confidence: 96%

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Hydrocarbon Synthesis from CO2 and H2 Using the Ultrafine Iron-Containing Catalytic Systems Based on Carbonized Cellulose

Куликова

Chudakova

Иванцов

et al. 2022

Eurasian Chem. Tech. J.

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Carbon materials were formed by the hydrothermal carbonization of cellulose, which were used as support for carbon dioxide hydrogenation catalysts (Fe/C and Fe-Mn/C). In the presence of these catalytic systems, CO2 conversion reached 50%. It is shown that the manganese introduction into the Fe-containing catalytic system significantly affects the distribution of gaseous С1-С4 products and liquid С5+ hydrocarbons. Promotion leads to the suppression of methane formation and an increase in the proportion of C2-C4 light olefins in gaseous products, as well as to intensification of secondary processes with the formation of a significant amount of iso-structures in liquid products. The different distribution of С1-С6 alcohols in the oxygen-containing products on the Fe/C and Fe-Mn/C catalysts indicates the manganese effect on the routes of their formation.

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Section: Resultsmentioning

confidence: 96%

“…Activated carbons, carbon black, graphite and graphitized materials are commonly used as carbon carriers [8]. For example, in the synthesis by the organic matric method the properties of the obtained materials are largely determined by the initial polymer choice and the conditions for its carbonization [9,10].…”

Section: Introductionmentioning

confidence: 99%

Hydrocarbon Synthesis from CO2 and H2 Using the Ultrafine Iron-Containing Catalytic Systems Based on Carbonized Cellulose

Куликова

Chudakova

Иванцов

et al. 2022

Eurasian Chem. Tech. J.

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Influence of MgO promoution to Ni-based composites in hydrogen production methane decomposition process

Sotnikova,

Ivantsov,

Kulikov

et al. 2024

International Journal of Hydrogen Energy

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Catalytic Activity of Thermolyzed [Co(NH3)6][Fe(CN)6] in CO Hydrogenation Reaction

et al. 2021

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Currently, the processes of obtaining synthetic liquid hydrocarbons and oxygenates are very relevant. Fischer-Tropsch synthesis (FTS) is the most important step in these processes. The products of thermal destruction in argon of the mixture [Co(NH3)6][Fe(CN)6] and Al(OH)3 were used as catalysts for CO hydrogenation. The resulting compositions were studied using powder X-ray diffraction, IR spectroscopy, elemental analysis, SEM micrographs. The specific surface area, pore and particle size distributions were determined. It was determined that the DCS-based catalysts were active in the high-temperature Fischer-Tropsch synthesis. The effect of aluminum in the catalyst composition on the distribution of reaction products was revealed.

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Properties of Cu-Co Composite Catalysts for Synthesis of Aliphatic Alcohols

Cited by 3 publications

References 0 publications

Hydrocarbon Synthesis from CO2 and H2 Using the Ultrafine Iron-Containing Catalytic Systems Based on Carbonized Cellulose

Hydrocarbon Synthesis from CO2 and H2 Using the Ultrafine Iron-Containing Catalytic Systems Based on Carbonized Cellulose

Influence of MgO promoution to Ni-based composites in hydrogen production methane decomposition process

Catalytic Activity of Thermolyzed [Co(NH3)6][Fe(CN)6] in CO Hydrogenation Reaction

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