Silver Complex of an N-Heterocyclic Carbene Ligand with Bulky Thiocarbamate Groups

Conformational Effects of [Ni2(μ‐ArS)2] Cores on Their Electrocatalytic Activity

“…Unsubstituted O ‐ and S ‐(2‐formylphenyl)‐ N , N ‐dimethylthiocarbamates ( a , R 1 =H, R 2 =H) were easily accessible from the corresponding phenol . The synthesis of the precursor 2,4‐disubstituted N , N ‐dimethylthiocarbamates ( a , R 1 =C 6 H 4 −(CF 3 ) 2 , R 2 =CH 3 ) was reported previously . 1 H (400 MHz) and 13 C{ 1 H} NMR (100 MHz) spectra were recorded on a Bruker 400 MHz Ultrashield™ NMR spectrometer by using the residual protiated solvent signal or tetramethylsilane (TMS) as internal references (TMS: δ =0.00 ppm, CHCl 3 : δ =7.26 ppm) at RT; subsequently, they were processed by using the MestReNova software from Mestrelab Research.…”

“…Proligand L 1 S tioc : In a 100 mL Schlenk flask, DME (≈50 mL) was transferred under N 2 , then c (1.000 g, 2.19 mmol; Scheme ) was added, followed by NaI (0.33 g, 2.19 mmol). After 1 h of stirring at RT, anilinium chloride (0.13 g, 0.10 mmol) and K 2 CO 3 (0.55 g, 3.99 mmol) were added; the solution was stirred at 80 °C for 7 days (monitored by TLC).…”