Intercalation of Molybdate Ions into Ni/Zn Layered Double Hydroxide Salts: Synthesis, Characterization, and Preliminary Catalytic Activity in Methyl Transesterification of Soybean Oil

Colombo, Kamila; Maruyama, Swami Arêa; Yamamoto, Carlos Itsuo

doi:10.21577/0103-5053.20160298

Cited by 5 publications

(10 citation statements)

References 23 publications

(35 reference statements)

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“…The bands located at 148, 397, 516, and 636 cm −1 in the spectra of the Na 2 MoO 4 /TiO 2 composites are attributed to the E g , B 1g , A 1g , and E g modes of the anatase phase TiO 2 [ 58 ]. The obvious peak at 895 cm −1 in the spectrum of the pure Na 2 MoO 4 powder is ascribed to the symmetric stretching modes of MoO 4 2− [ 59 ]. Correspondingly, for the spectra of the Na 2 MoO 4 –15.4%-TiO 2 , Na 2 MoO 4 –24.1%-TiO 2 and Na 2 MoO 4 –41.4%-TiO 2 samples, the stretching vibration peaks at 892, 929, and 950 cm −1 all belong to the symmetric stretching modes of MoO 4 2− , which display slight shifts as compared with that of the pure Na 2 MoO 4 powder, demonstrating the strong interaction between MoO 4 2− and TiO 2 .…”

Section: Resultsmentioning

confidence: 99%

A Bio-Inspired Nanotubular Na2MoO4/TiO2 Composite as a High-Performance Anodic Material for Lithium-Ion Batteries

2021

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A train of bio-inspired nanotubular Na2MoO4/TiO2 composites were synthesized by using a natural cellulose substance (e.g., commercial ordinary filter paper) as the structural template. The TiO2 gel films were coated on the cellulose nanofiber surfaces via a sol-gel method firstly, followed with the deposition of the poly(diallyldimethylammonium chloride)/Na2MoO4 (PDDA/Na2MoO4) bi-layers several times, through the layer-by-layer self-assembly route, yielding the (PDDA/Na2MoO4)n/TiO2-gel/cellulose composite, which was calcined in air to give various Na2MoO4/TiO2 nanocomposites containing different Na2MoO4 contents (15.4, 24.1, and 41.4%). The resultant nanocomposites all inherited the three-dimensionally porous network structure of the premier cellulose substance, which were formed by hierarchical TiO2 nanotubes anchored with the Na2MoO4 layers. When employed as anodic materials for lithium-ion batteries, those Na2MoO4/TiO2 nanocomposites exhibited promoted electrochemical performances in comparison with the Na2MoO4 powder and pure TiO2 nanotubes, which was resulted from the high capacity of the Na2MoO4 component and the buffering effects of the TiO2 nanotubes. Among all the nanotubular Na2MoO4/TiO2 composites, the one with a Na2MoO4 content of 41.4% showed the best electrochemical properties, such as the cycling stability with a capacity of 180.22 mAh g−1 after 200 charge/discharge cycles (current density: 100 mA g−1) and the optimal rate capability.

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Section: Resultsmentioning

confidence: 99%

A Bio-Inspired Nanotubular Na2MoO4/TiO2 Composite as a High-Performance Anodic Material for Lithium-Ion Batteries

2021

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“…The basal spacing in the NiZn-LDH decreased from 13.08 Å to ca. 9.5 Å regardless of the working pH, [85], which might suggest the intercalation of hydrated molybdate anions. The as-synthesized material and the solid that was obtained by thermal treatment at 250 • C (basal spacing reduced to 7.35 Å due to dehydration) were tested as catalysts for the methyl transesterification of soybean oil [85].…”

Section: Molybdatesmentioning

confidence: 95%

“…This behavior might be ascribed to the increased surface Brønsted acidity and the specific surface area shown by the Mo-containing sample [18,86]. Colombo et al [85] prepared at two different pH values a NiZn LDH initially intercalated with acetate ions, which were subsequently replaced with molybdate anions via an ion exchange reaction. The basal spacing in the NiZn-LDH decreased from 13.08 Å to ca.…”

Section: Molybdatesmentioning

confidence: 99%

“…The as-synthesized material and the solid that was obtained by thermal treatment at 250 • C (basal spacing reduced to 7.35 Å due to dehydration) were tested as catalysts for the methyl transesterification of soybean oil [85]. All of the materials were catalytically active and led to high conversions of the substrate, but poor selectivities [85].…”

Section: Molybdatesmentioning

confidence: 99%

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Highlights on the Catalytic Properties of Polyoxometalate-Intercalated Layered Double Hydroxides: A Review

et al. 2020

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Layered double hydroxides (LDH) are an extended class of two-dimensional anionic materials that are known for their unique lamellar structure, versatile composition, and tunable properties. The layered architecture allows the intercalation between the positively charged sheets of a vast variety of anionic species, including oxometalates and polyoxometalates (POM). The hybrid composites that were developed using POM and LDH show great advantages when compared to both parent materials causing the appearance of new functionalities, which may lead to remarkable contributions in many areas of application, especially in catalysis. The current review paper emphases all of the crucial works already existing in literature that are related to the large group of POM-LDH solids and their use as catalysts for fine organic synthesis. The new trends in the development of the POM-LDH catalysts are highlighted based on the overview of 121 scientific articles that were published between 1984 and 2019. The main topics are focused primarily on the synthesis, characterization, and the catalytic applications of different LDH systems hosting polyoxometalates with low, medium, and high nuclearity. The intense exploration of the POM-LDH field has led to the obtaining of countless effective catalysts used in various types of reactions, from condensation, esterification, halodecarboxylation, to oxidation and epoxidation.

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“…The FTIR spectrum of ZHM-E3 (b) maintained the absorption band at 3440 cm –1 assigned to OH stretching vibrations, since only the interlayer anions were exchanged and the layers’ structure was preserved intact. A broad and strong absorption band was observed at 803 cm –1 , regarding the antisymmetric stretching vibrations of MoO bonds, confirming the presence of the interlayer molybdate anions. − ,, Moreover, an absorption band could be observed at 1633 cm –1 , which can be assigned to the interlayer water bending vibration mode. , This absorption band was not identified in the spectrum of ZHA (a), probably because it was superimposed by the strong absorption band of the carboxylate group in the same region …”

Section: Results and Discussionmentioning

confidence: 94%

Zinc-Layered Hydroxide Salt Intercalated with Molybdate Anions as a New Smart Nanocontainer for Active Corrosion Protection of Carbon Steel

Leal

Marino

2020

ACS Appl. Mater. Interfaces

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The use of smart nanocontainers to store corrosion inhibitors in coatings significantly increases the efficiency and durability of the coating, providing active corrosion protection.Here we report the synthesis of a zinc-layered hydroxide salt (LHS) and its use as a novel nanocontainer for this purpose, storing the corrosion inhibitor molybdate in the interlayer region of the LHS. Layered zinc hydroxide molybdate (ZHM) was obtained by anion-exchange reactions using layered zinc hydroxide acetate (ZHA) as a precursor, obtained by alkaline coprecipitation. The release behavior of molybdate from the ZHM nanocontainers in aqueous NaCl solution (0.05 mol/L) was evaluated using UV− vis absorption spectroscopy. The molybdate release from the ZHM nanocontainers was realized by the anion-exchange mechanism, where chloride anions replaced intercalated molybdate anions. The release was fast in the first minutes of exposure, followed by a controlled release afterward, reaching about 35% of cumulative amount of released molybdate after 30 days of exposure. The anticorrosion effect provided by the ZHM nanocontainers for carbon steel was investigated by electrochemical impedance spectroscopy. The steel substrate was coated with an epoxy resin loaded with ZHM nanocontainers (5 wt %) and immersed in an NaCl solution (0.05 mol/L) to evaluate the active mechanisms of inhibition and the anticorrosion properties of the loaded coating in comparison with a neat coating (blank). The coating loaded with ZHM nanocontainers presented the best corrosion protection performance, exhibiting an increase of R C (coating resistance) with the immersion time and superior R P (polarization resistance) for all the measured periods, compared to the blank. This effect is a consequence of the double mechanism of protection provided by the ZHM nanocontainers: (i) stimulus-response release of molybdate and its active inhibition in the scratched region by the formation of an insoluble protective film, simultaneously with (ii) removal of the corrosive chloride species from the medium.

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Intercalation of Molybdate Ions into Ni/Zn Layered Double Hydroxide Salts: Synthesis, Characterization, and Preliminary Catalytic Activity in Methyl Transesterification of Soybean Oil

Cited by 5 publications

References 23 publications

A Bio-Inspired Nanotubular Na2MoO4/TiO2 Composite as a High-Performance Anodic Material for Lithium-Ion Batteries

A Bio-Inspired Nanotubular Na2MoO4/TiO2 Composite as a High-Performance Anodic Material for Lithium-Ion Batteries

Highlights on the Catalytic Properties of Polyoxometalate-Intercalated Layered Double Hydroxides: A Review

Zinc-Layered Hydroxide Salt Intercalated with Molybdate Anions as a New Smart Nanocontainer for Active Corrosion Protection of Carbon Steel

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