Observação De Homodímero Do Tipo Bis-1,3-Benzodioxona Sintetizado via Metátese De Olefinas Da Piperina Catalisada Por Pré-Catalisadores De Ru(ii) Não Comerciais
Abstract:OBSERVATION OF BIS-1,3-BENZODIOXONE TYPE HOMODIMER SYNTHESIZED VIA PIPERINE OLEFIN METATHESIS CATALYZED BY NON-COMMERCIAL Ru(II) PRE-CATALYSTS. LN-1 and LN-2 are two Ru(II) complexes coordinated to the phosphine and amines simultaneously, each with two chlorides. PPh3 is the phosphine and the amine is piperidine (LN-1) and perhydroazepine (LN-2). The two compounds are complexes five-coordinated square pyramidal geometry, with the amine in the axial plane. LN-1 and LN-2 were tested for the first time as initiat… Show more
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