Sustainable production of furfural and 5-hidroximetilfurfural from rice husks and soybean peel by using ionic liquid

Scapin, Elisandra; Rambo, Magale Karine Diel; Viana, Guenther Carlos Couto; Marasca, Nicole; Lacerda, Gabriela Eustáquio; Rambo, Michele Cristiane Diel; Fernandes, Rachel de Moura Nunes

doi:10.1590/fst.04419

Cited by 12 publications

(7 citation statements)

References 36 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Biochar yield (%) was defined through equation 8. (8) wherein: P 0 : initial mass and P 1 : final mass.…”

Section: Pyrolysis Processmentioning

confidence: 99%

“…Both bioproducts are excellent platform chemicals, since they can be transformed into fuel additives such as furfural alcohol, ethyllevulinate, levulinic acid and tetrahydrofuran. 7,8 The solid residual material that remains after hydrolysis, which is known as residue hydrolyzation (RH) process, is mainly composed of lignin. 9 This material can be pyrolyzed to enable the production of energy and platform chemicals (bio-oil and biochar).…”

Section: Introductionmentioning

confidence: 99%

See 1 more Smart Citation

Sustainability of Biorefinery Processes Based on Baru Biomass Waste

Rambo¹,

Rambo²,

Melo³

et al. 2020

J. Braz. Chem. Soc.

Self Cite

View full text Add to dashboard Cite

The aims of the current study are to investigate the composition of biomass from baru processing and to explore the feasibility of valuing it through the development of bioproducts such as fermentable sugars, furanics and biochar. Baru (Dipteryx alata Vog.) waste (endocarp and mesocarp) has great energetic potential to produce bioproducts due to its chemical composition. Proximate analyses applied to such waste have found low favorable moisture and ash content in it. Bioproduct characterizations after acid hydrolysis have shown that baru endocarp and mesocarp biomass can enable a range of value-added products in biorefinery concepts such as furfural and 5-hydroximetylfurfural (20.0 and 1.5% yield, respectively), and high sugar content (approximately 19.15 and 38.40%, respectively). Pyrolysis processes also present high biochar content (ca. 48%), with satisfactory characteristics to be used as fuel, as well as calorific value higher than 30 kJ g-1 .

show abstract

“…Biochar yield (%) was defined through equation 8. (8) wherein: P 0 : initial mass and P 1 : final mass.…”

Section: Pyrolysis Processmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Sustainability of Biorefinery Processes Based on Baru Biomass Waste

Rambo¹,

Rambo²,

Melo³

et al. 2020

J. Braz. Chem. Soc.

Self Cite

View full text Add to dashboard Cite

show abstract

“…Furfuryl alcohol (2(3H)-furanone, 5-methyl) is also an alcohol produced from the fermentation of rice husk. The compound was known to be a product from biocatalytic reduction of furfural which could be produced by microbial conversion of pentosan, a pentose sugar from hemicellulose of rice husk substrate as reported from another research (Xue-Ying et al, 2019;Elisandra et al, 2019). The compound has been in use by foods industries, pharmaceutical industries as fragrance agent as well as in the production of other valuable chemicals such as ethyl furfuryl ether, tetrahydrofurfuryl alcohol (Maris et al, 2016).…”

Section: Discussionmentioning

confidence: 98%

Microbial production of 2,3-butanediol from rice husk using anaerobic Clostridium species

Sanusi¹,

Farouq²,

Bazata³

et al. 2021

Int. J. Bio. Chem. Sci

View full text Add to dashboard Cite

Interest in the area of biomass based-product production is increasing all over the world due to the environmental challenges posed by fossil fuel and fear of its extinction. Production of biofuel and other compounds especially from agricultural waste can reduce these environmental problems because of its sustainability and environmentally friendliness. One of the major petrochemical product widely used in many industries is 2,3-butanediol and was found to be produced from agricultural wastes by microorganisms. Therefore, Microbial production of 2,3-butanediol from rice husk using Clostridium species was investigated in this research. Structural composition of the rice husk was determined before and after pretreatment. Hemicellulose and lignin content of rice husk was determined after extraction while cellulose was determined as the difference from the extractives, hemicelluloses and lignin. Dilute (2%) NaOH was used for the pretreatment of rice husk. Hydrolysis was carried out using Aspergillus niger and reducing sugar released was determined using standard method with UV-VIS spectrophotometer. Clostridium species was isolated from sugarcane bagasse, identified using basic morphological and molecular biology techniques. The fermentation of rice husk was performed using the Clostridium species. Fermentation by-product was determined using Gas Chromatography Mass-spectrometry. Cellulose content increased from 32% before pretreatment to 53.3% after pretreatment, lignin increased from 8.4% before pretreatment to 30.7% after pretreatmemt and hemicellulose decreased from 30% before pretreatment to 8% after pretreatment. A total of 1.05 g/l of reducing sugar was released after enzymatic hydrolysis of the rice husk with Aspergillus niger. Alcohol 2,3-butanediol (0.6%) and Furfuryl alcohol (0.45%) were detected in the by-product of fermentation. Other compounds detected are fatty acids that ranges from C16 to C25 with 9,12-Octadecanoic acid as the major fatty acid. From the results of this work, Rice husk was found to have substantial amount of sugar (cellulose and hemicelluce) that can be converted to valuable product including 2,3-butanediol. Keywords: Biofuel, Bio-refinary, Cellulose, Clostrudium, fermentation.

show abstract

“…Wang et al 47 obtained HMF in about 23% yield from wheat straw using IL 1-butyl-3-methylimidazole chloride ([BMIM][Cl]). Rambo et al 48 obtained HMF and FF yielding 1.5 and 20.0%, respectively, using baru biomass residues, ionic liquid, in an oil bath at 120-140 °C for reaction times of 1-2 h. In a paper by Scapin et al, 36 the best yields for FF production from rice husks were obtained with 4 h of reaction at 120 °C (34%) and for soy peel with 3 h of reaction at 120 °C (59%). In this same work, HMF was produced with yields of 8.7 and 3.4% for rice and soy husks, respectively.…”

Section: Ftir Spectroscopymentioning

confidence: 99%

Production of Furanic Compounds and Organic Acids from Brazilian Pequi (Caryocar brasiliensis Camb.) Residues Using Green Chemistry

Scapin¹,

Rambo²,

Viana³

et al. 2020

J. Braz. Chem. Soc.

Self Cite

View full text Add to dashboard Cite

In the current search for renewable energy sources, residual biomass has gained ground in the concept of biorefinery. Furanic compounds such as 5-hydroxymethylfurfural (HMF), furfural (FF) and derivatives such as levulinic acid (LA), obtained from biomass, have emerged as important industrial chemical platforms. In this sense, this work aimed to use pequi bark, typical biomass and abundant in the Brazilian cerrado, in the production of HMF, FF and LA using the ionic liquid 1-n-butyl-3-methyl-imidazole bromide ([BMIM][Br]). The analysis of chemical composition of pequi bark showed that it has potential for use in the production of bioproducts, FF, HMF and LA, with yields of 65, 3 and 23.7%, respectively. High glucose conversion rates were found (> 90%). The analysis of variance (ANOVA) was applied to obtain the mathematical model with α = 0.05, verifying the significance of the second order model established for HMF (F = 0.00167) and FF (0.004494). The model fit is satisfactory, obtaining the coefficient of determination (R 2) for the HMF and for the FF of 0.9599 and 0.08422, respectively. From the results obtained, it can be concluded that pequi bark has good precursor capacity for use in biorefinery processes.

show abstract

Sustainable production of furfural and 5-hidroximetilfurfural from rice husks and soybean peel by using ionic liquid

Cited by 12 publications

References 36 publications

Sustainability of Biorefinery Processes Based on Baru Biomass Waste

Sustainability of Biorefinery Processes Based on Baru Biomass Waste

Microbial production of 2,3-butanediol from rice husk using anaerobic Clostridium species

Production of Furanic Compounds and Organic Acids from Brazilian Pequi (Caryocar brasiliensis Camb.) Residues Using Green Chemistry

Contact Info

Product

Resources

About