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The blast furnace sludge is a waste generated after the washing step of the blast furnace gas. The reuse of this waste in the steelmaking process itself is quite problematic. This study aims to analyze the possibility of the incorporation of a type of blast furnace sludge, benefited by a process that uses helical separators, into red ceramic. Specimens were prepared by uniaxial pressing at 20 MPa and then fired at 750°C and 950°C. The evaluated technological properties were linear shrinkage, water absorption and flexural rupture strength. The results showed that the benefited blast furnace sludge significantly influences the evaluated properties, by impairing the linear shrinkage and the water absorption but improving the mechanical strength.
The blast furnace sludge is a waste generated after the washing step of the blast furnace gas. The reuse of this waste in the steelmaking process itself is quite problematic. This study aims to analyze the possibility of the incorporation of a type of blast furnace sludge, benefited by a process that uses helical separators, into red ceramic. Specimens were prepared by uniaxial pressing at 20 MPa and then fired at 750°C and 950°C. The evaluated technological properties were linear shrinkage, water absorption and flexural rupture strength. The results showed that the benefited blast furnace sludge significantly influences the evaluated properties, by impairing the linear shrinkage and the water absorption but improving the mechanical strength.
The microstructure of a clay ceramic added with blast furnace sludge, a residue generated at integrate steel making plants, has been analyzed. This analysis was performed by means of optical microscopy and scanning electron microscopy coupled with energy dispersive spectroscopy. The green clay body was added with 5 and 10 wt% of blast furnace sludge. A pure clay body was also considered as reference. These clay bodies were fired at 750°C and 950°C. The results indicated that the ceramic microstructure is non-uniform with both residue particles and pores dispersed throughout the clay matrix. Microcracks are also observed as a consequence of weak adhesion of the residue to the clay. At the higher firing temperature of 950°C the microstructure displayed a smoother surface due to the formation of low melting phases.
The blast furnace is one the main systems used in steelmaking plants operating with iron ores. In addition to the production of pig iron and slag, the blast furnace operation also generates a considerable amount of wastes such as dust usually collected in the upwards flowing gas. The dust collecting stage, without separation procedures, produces a sludge, which cannot be recycled inside the plant due to the concentration of undesirable earth alkaline metals as well as zinc. A possible solution for this so-called global blast furnace sludge (GFS) is its incorporation, outside the plant, into clayey ceramic products processed at high temperatures. Therefore, the objective of the present work was to investigate the effect of GFS incorporation, in amounts of 5 and 10 wt%, into kaolinitic clay ceramics fired at 750, 950 and 1050oC. Initially, the GFS was characterized and, after processing, incorporated into ceramics that were then tested for the water absorption, linear shrinkage and flexural strength. It was found significant improvements in the properties for GFS incorporated ceramics fired at 1050oC.
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