Production of allyl phenyl carbinol (APC) by biotrans-formation using Rhizopus arrhizus

Shukla, V.B.; Kulkarni, P. R.

doi:10.1590/s1516-89132000000300001

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Ester Hydrolysis1

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2009

2010

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Cited by 2 publications

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References 13 publications

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“…The incubation of (±) binaphthol diacetates (159 and 162) with R. oryzae resulted in the enantiospecific hydrolysis of the S-acetoxy groups to afford the optically active binaphthol 161 and 164 respectively (Scheme 17) in high optical purity [50]. Stereoselective hydrolysis of (±)-1-phenyl-3-butene-1-ol 165 by the fungus afforded (R)-(+)-1-phenyl-3-butene-1-ol (166) (49%, 56% ee) [51], while hydrolysis of (±)-sulcatol acetate (167) by Rhizopus yielded (R)-(-)-sulcatol (168) (50%, 65% ee) after 24 h [47].…”

Section: Ester Hydrolysismentioning

confidence: 99%

Biotransformation Reactions by Rhizopus spp.

Martin

2010

COC

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The Rhizopus spp., in particular Rhizopus oryzae, are among the most frequently used whole cell biocatalysts. The fungus is known to catalyze the bioconversion of various reactive and non-reactive substrates with high regio-and stereoselectivities. The range of products obtained from these reactions has been attributed to the substrate binding modes within the enzyme's active site. More recently, an active site model has been developed to account for the reported bioconversions. The use of this model will prove useful in future synthetic and biotechnological applications.

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Section: Ester Hydrolysismentioning

confidence: 99%