Commercial cellulosic biofuel operation
requires a reliable, low-cost,
and stable feedstock logistic system. One great challenge is its long-term
storage at least for one harvest cycle (1 year for agricultural crop
residues) with a minimum loss of bulky, geographically dispersed,
inflammable, and easily degradable lignocellulosic biomass. This study
conducted an investigation of year-round storage of the agricultural
crop residue feedstock under the scenario of performing dry acid pretreatment
at the distributed regional collection depots, instead of the central
biorefinery plant. The dry acid pretreatment method provides a practical
basis for the storage operation by its ability for high preservation
of polysaccharide solids, highly compacted accumulation density, being
free from wastewater generation, low capital investment, and low energy
consumption. Three major agricultural crop residues (corn stover,
wheat straw, and rice straw) were pretreated by dry acid pretreatment
and then stored in their major planting regions under varying natural
conditions of temperature, rain and snow fall, humidity, wind, and
sunlight. The pretreated corn stover, wheat straw, and rice straw
contained approximately 50% (w/w) of moisture, and their high water
absorption capacity maintained the crop residues in solid and fine-particle
forms without free wastewater generation and flammability. Meanwhile,
the pretreated crop residues were of low pH value and contained various
inhibitory compounds for microbial growth. The results show that the
crop residue feedstocks were well preserved with negligible solid
and fermentable sugar loss after year-round storage in different regions.
The physical properties, chemical compositions, enzymatic hydrolysis
yields, and ethanol fermentability were maintained essentially constant
with a few positive exceptions such as the increased hydrolysis yield
and reduced inhibitor content. A case study shows that the feedstock
transportation cost of the long-term stored feedstocks under the scenario
of dry acid pretreatment at collection depots was significantly reduced
compared to that of the direct transportation of virgin crop residual
feedstocks. This study provided an efficient and practical logistic
system for large-scale biorefinery plants.