Gravitational and magnetic separation in self-assembled clay-ferrofluid nanocomposites

Abstract

We report on experimental observations of self-assemblies in colloidal dispersions of clay nanoplatelets and magnetic nanoparticles. Visual observations have been combined with small angle X-ray scattering (SAXS) in the study of several composites at a fixed clay concentration in the dilute regime, and varying ferrofluid concentrations. Our visual observations which encompass macroscopic separation in gravitational-and magnetic field, indicate that all samples present a concentrated phase and a diluted one. SAXS data obtained from each phase are consistent with the interpretation that the scattering contribution from the clay nano-platelets in the samples can be neglected in comparison with the magnetic particle contribution. The analysis of the scattered intensity is performed combining two models, one based on the global scattering function and the other allowing the extraction of the structure factor of the mixtures. The parameters of the size distribution of magnetic nanoparticles determined by both methods are in good agreement. The structure factor of the mixtures shows that on a local scale, the mixtures behave like a gas of isolated magnetic nanoparticles. It also indicates the presence of interactions between magnetic nanoparticles mediated by the presence of Laponite platelets. Such interactions could be attributed with a progressive partial phase separation between spheres and discs rather than to the formation of dense aggregates.

SAXS Analysis of Magnetic Field Influence on Magnetic Nanoparticle Clusters

“…This work aims to investigate the local structure of magnetic colloids [22] under external magnetic field application, the colloids in question are composed of magnetic nanoparticles based on manganese ferrite type core-shell MnFe 2 O 4+δ @γ-Fe 2 O 3 [23] and dispersed in aqueous medium. SAXS measurements were performed with external magnetic field applied [24] to determine the dimensions between nanoparticles and clusters [25], for future studies in hyperthermia [26] for biomedical applications.…”

Small-angle X-ray and small-angle neutron scattering investigations of colloidal dispersions of magnetic nanoparticles and clay nanoplatelets

“…The ionic strength and pH conditions needed to obtain a stable isotropic liquid dispersion of magnetic nanoparticles and laponite nanoplatelets are described elsewhere (Paula et al, 2007). Our composite materials were obtained by mixing an isotropic liquid dispersion of laponite at 0.1 wt% and a ferrofluid solution with a fraction of magnetic nanoparticles of 0.025 wt%.…”

Estudo da microestrutura de nanocoloides magnéticos por espalhamento de raio-x em baixo ângulo

“…Assim, considera-se esferas seguindo uma distribuição log-normal designada por 2 : onde σ é a polidispersão e D 0 é o diâmetro médio. O fator de forma é adaptado [66] em função da distribuição log-normal por:…”