“…These qualities were attributed to the excellent stability of the Fe(III)Zn(II) complex employed to mimic the active site of the enzyme purple acid phosphatase. In addition, this sensor shows better analytical performance compared with other biosensors and sensors reported in the literature [17][18][19][20][21]34]. …”
Section: Repeatability Reproducibility and Stability Of The Biomimetmentioning
confidence: 97%
“…In recent years our group has described in the literature the construction and application of several biosensors and biomimetic sensors based on a carbon paste (CP) [17][18][19][20][21]. Three types of carbon paste electrodes were constructed: one with and one without the Fe(III)Zn(II) complex, and another modified with Fe(III) and Zn(II) perchlorate.…”
Section: Biomimetic Sensor Preparationmentioning
confidence: 99%
“…Also, they do not require substantial sample preparation and facilitate analysis in mixtures and complex matrices. Furthermore, the coupling of electrochemical methods with the intrinsic selectivity and sensitivity of our enzymatic mimetic catalyst reactions is promising for the construction of a lowcost and simple biomimetic sensor [17][18][19][20][21].…”
“…These qualities were attributed to the excellent stability of the Fe(III)Zn(II) complex employed to mimic the active site of the enzyme purple acid phosphatase. In addition, this sensor shows better analytical performance compared with other biosensors and sensors reported in the literature [17][18][19][20][21]34]. …”
Section: Repeatability Reproducibility and Stability Of The Biomimetmentioning
confidence: 97%
“…In recent years our group has described in the literature the construction and application of several biosensors and biomimetic sensors based on a carbon paste (CP) [17][18][19][20][21]. Three types of carbon paste electrodes were constructed: one with and one without the Fe(III)Zn(II) complex, and another modified with Fe(III) and Zn(II) perchlorate.…”
Section: Biomimetic Sensor Preparationmentioning
confidence: 99%
“…Also, they do not require substantial sample preparation and facilitate analysis in mixtures and complex matrices. Furthermore, the coupling of electrochemical methods with the intrinsic selectivity and sensitivity of our enzymatic mimetic catalyst reactions is promising for the construction of a lowcost and simple biomimetic sensor [17][18][19][20][21].…”
“…A cadeia da quitosana admite um grande número de modificações químicas através dos diferentes grupamentos funcionais distribuídos sobre o anel glicopiranosídeo. A estrutura macromolecular pode ser manipulada, mediante a introdução de novos grupos funcionais de interesse, para conferir aos derivados, características que atendam às aplicações finais [79][80][81][82].…”
Section: Reatividade E Modificações Químicasunclassified
The effectiveness of the protected amino group on crosslinked chitosans for copper removal and the thermodynamics of interaction at the solid/liquid interface, Carbohydrate Polymers, 77 ( 2009) 760.
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