A síntese do aduto binuclear [Fe(CNBu t)(CO)4(HgSO4 )]

Abstract

Recebido em 19/11/99; aceito em 15/2/01 SYNTHESIS OF THE BINUCLEAR [Fe(CNBu t)(CO) 4 (HgSO 4)] ADDUCT. The binuclear [Fe(CNBu t)(CO) 4 (HgSO 4)] adduct was obtained in the reaction of HgSO 4 with [Fe(CNBu t)(CO) 4 ] in methanol. This adduct, without a similar in the homoleptic pentacarbonyliron, was characterized by analytical and spectroscopic data. Further Mössbauer and molar conductivity studies have confirmed it's adduct nature.