(1'S,4S)-2-Aryl-4-(1'-hydroxybenzyl)-4,5-dihydrooxazole as a Useful Chiral Auxiliary for the Synthesis of b-Amino Acids and b-Lactams in a Highly Stereoselective Manner

stereochemistry stereochemistry (general, optical resolution) O 0030 07 -038 (1'S,4S)-2-Aryl-4-(1'-hydroxybenzyl)-4,5-dihydrooxazole as a Useful Chiral Auxiliary for the Synthesis of β-Amino Acids and β-Lactams in a Highly Stereoselective Manner. -The addition reaction of lithium amide or the imine (V) to the substrates (I) or (IV) bearing a chiral auxiliary derived from (1S,2S)-2-amino-1-phenylpropane-1,3-diol generates β-amino acid esters (III) or β-lactams (VI) in moderate stereoselectivity. -(SHIMIZU, M.; MARUYAMA, S.; SUZUKI, Y.; FUJISAWA, T.; Heterocycles 45 (1997) 10, 1883-1889; Dep. Chem. Mater., Fac. Eng., Mie Univ., Tsu, Mie 514, Japan; EN)

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ChemInform Abstract: (1′S,4S)‐2‐Aryl‐4‐(1′‐hydroxybenzyl)‐4,5‐dihydrooxazole as a Useful Chiral Auxiliary for the Synthesis of β‐Amino Acids and β‐Lactams in a Highly Stereoselective Manner.

Shimizu

Maruyama

Suzuki

et al. 1998

ChemInform

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A new synthesis of N‐phenyl lactams

Markgraf

Stickney

2000

Journal of Heterocyclic Chem

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Synthesis of chiral (7R)-[η6-5-(N,N-dimethylamino)-7-formyl-1,3-benzodioxole]chromium complex and its application in the synthesis of optically active cis-β-lactams

Costa

Curto

et al. 2001

Journal of Organometallic Chemistry

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(1'S,4S)-2-Aryl-4-(1'-hydroxybenzyl)-4,5-dihydrooxazole as a Useful Chiral Auxiliary for the Synthesis of b-Amino Acids and b-Lactams in a Highly Stereoselective Manner

Cited by 6 publications

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ChemInform Abstract: (1′S,4S)‐2‐Aryl‐4‐(1′‐hydroxybenzyl)‐4,5‐dihydrooxazole as a Useful Chiral Auxiliary for the Synthesis of β‐Amino Acids and β‐Lactams in a Highly Stereoselective Manner.

ChemInform Abstract: (1′S,4S)‐2‐Aryl‐4‐(1′‐hydroxybenzyl)‐4,5‐dihydrooxazole as a Useful Chiral Auxiliary for the Synthesis of β‐Amino Acids and β‐Lactams in a Highly Stereoselective Manner.

A new synthesis of N‐phenyl lactams

Synthesis of chiral (7R)-[η6-5-(N,N-dimethylamino)-7-formyl-1,3-benzodioxole]chromium complex and its application in the synthesis of optically active cis-β-lactams

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