“…The rate constants for MB photodegradation with Ni-SDZ under visible light are − 0.01634 min −1 . The values of k indicated that the activity of photocatalyst Ni-SDZ is better than that of reported data 58 , 91 , 98 – 100 . Figure 12 ( a ) Absorption spectra of MB solution with Ni-SDZ complex function of visible light irradiation time, ( b ) Photocatalytic degradation rate of MB in the presence of Ni-SDZ complex, ( c ) The liner fitting of -in C/C o and irradiation time and ( d ) Starting and final degradation % V/S time and ( e ) Degradation pathway of MB dye via Chromophoric group degradation.…”
Section: Photo-catalytic Degradationcontrasting
confidence: 55%
“…The surface represented by a deep red spot is illuminating hydrogen bonding interactions (Fig. 5 ) 58 , 78 . The dominant interactions are H…O can be seen in di and de surface plots as the bright red spots and deep red spots in maps are showing strong interactions in molecules.…”
Section: Resultsmentioning
confidence: 99%
“…The flow time of each sample was automatically measured with three repetitions and the viscosity of the samples was computed by the average values of three measurements. The results were presented as relative specific viscosity (η/η 0 ) 1/3 against 19 /[DNA] = 0, 0.4, 0.8, 1.2, 1.6, 2.0, where η and η 0 are the specific viscosities of DNA in the presence and absence of the compound respectively 54 – 58 .…”
A 3D-supramolecular nickel integrated Ni-SDZ complex was synthesized using sodium salt of sulfadiazine as the ligand and nickel(II) acetate as the metal salt using a condensation process and slow evaporation approach to growing the single crystal. The metal complex was characterized for its composition, functional groups, surface morphology as well as complex 3D structure, by resorting to various analytical techniques. The interacting surface and stability as well as reactivity of the complex were carried out using the DFT platform. From ADMET parameters, human Intestinal Absorbance data revealed that the compound has the potential to be well absorbed, and also Ni-SDZ complex cannot cross the blood–brain barrier (BBB). Additionally, the complex's DNA binding affinity and in-vivo and in-vitro cytotoxic studies were explored utilizing UV–Vis absorbance titration, viscosity measurements, and S. pombe cells and brine shrimp lethality tests. In visible light radiation, the Ni-SDZ complex displayed exceptional photo-degradation characteristics of approximately 70.19% within 70 min against methylene blue (MB).
“…The rate constants for MB photodegradation with Ni-SDZ under visible light are − 0.01634 min −1 . The values of k indicated that the activity of photocatalyst Ni-SDZ is better than that of reported data 58 , 91 , 98 – 100 . Figure 12 ( a ) Absorption spectra of MB solution with Ni-SDZ complex function of visible light irradiation time, ( b ) Photocatalytic degradation rate of MB in the presence of Ni-SDZ complex, ( c ) The liner fitting of -in C/C o and irradiation time and ( d ) Starting and final degradation % V/S time and ( e ) Degradation pathway of MB dye via Chromophoric group degradation.…”
Section: Photo-catalytic Degradationcontrasting
confidence: 55%
“…The surface represented by a deep red spot is illuminating hydrogen bonding interactions (Fig. 5 ) 58 , 78 . The dominant interactions are H…O can be seen in di and de surface plots as the bright red spots and deep red spots in maps are showing strong interactions in molecules.…”
Section: Resultsmentioning
confidence: 99%
“…The flow time of each sample was automatically measured with three repetitions and the viscosity of the samples was computed by the average values of three measurements. The results were presented as relative specific viscosity (η/η 0 ) 1/3 against 19 /[DNA] = 0, 0.4, 0.8, 1.2, 1.6, 2.0, where η and η 0 are the specific viscosities of DNA in the presence and absence of the compound respectively 54 – 58 .…”
A 3D-supramolecular nickel integrated Ni-SDZ complex was synthesized using sodium salt of sulfadiazine as the ligand and nickel(II) acetate as the metal salt using a condensation process and slow evaporation approach to growing the single crystal. The metal complex was characterized for its composition, functional groups, surface morphology as well as complex 3D structure, by resorting to various analytical techniques. The interacting surface and stability as well as reactivity of the complex were carried out using the DFT platform. From ADMET parameters, human Intestinal Absorbance data revealed that the compound has the potential to be well absorbed, and also Ni-SDZ complex cannot cross the blood–brain barrier (BBB). Additionally, the complex's DNA binding affinity and in-vivo and in-vitro cytotoxic studies were explored utilizing UV–Vis absorbance titration, viscosity measurements, and S. pombe cells and brine shrimp lethality tests. In visible light radiation, the Ni-SDZ complex displayed exceptional photo-degradation characteristics of approximately 70.19% within 70 min against methylene blue (MB).
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