1-alkylhydroxy(thioxy)-2,2,2-trichloroetylacetates (trichloroacetates) and their effect on the properties of lubricants

Facile One-Pot Synthesis of S-Alkyl Thiocarbamates

“…13 C NMR δ: 189.3, 94.9, 31.7, 31.2, 28.5, 28.4, 22.4, 13.9 δ. Bp: 137 °C/1 Torr (lit. 22 After the mixture was stirred for 5 min at rt, 3.80 mmol of the corresponding amine was rapidly added. The reaction was rapidly stirred at the indicated temperature for 24 h (see Table 1).…”

“…1 H NMR δ: 3.04 (t, J = 6, 2H), 2.68 (dt, 2H), 1.48−1.27 (m, 6H), 0.92 δ (t, J = 6, 3H). 13 C NMR δ: 189.3, 94.9, 31.7, 31.2, 28.5, 28.4, 22.4, 13.9 δ. Bp: 137 °C/1 Torr (lit . bp 104 °C/0.4 Torr).…”