“…13 C NMR δ: 189.3, 94.9, 31.7, 31.2, 28.5, 28.4, 22.4, 13.9 δ. Bp: 137 °C/1 Torr (lit. 22 After the mixture was stirred for 5 min at rt, 3.80 mmol of the corresponding amine was rapidly added. The reaction was rapidly stirred at the indicated temperature for 24 h (see Table 1).…”
We report a novel one-pot two-step synthesis of a variety of S-alkyl thiocarbamates. This method offers a two-directional approach making use of trichloroacetyl chloride, requires no complex starting material, incorporates a variety of substituents, and proceeds in high yields.
“…13 C NMR δ: 189.3, 94.9, 31.7, 31.2, 28.5, 28.4, 22.4, 13.9 δ. Bp: 137 °C/1 Torr (lit. 22 After the mixture was stirred for 5 min at rt, 3.80 mmol of the corresponding amine was rapidly added. The reaction was rapidly stirred at the indicated temperature for 24 h (see Table 1).…”
We report a novel one-pot two-step synthesis of a variety of S-alkyl thiocarbamates. This method offers a two-directional approach making use of trichloroacetyl chloride, requires no complex starting material, incorporates a variety of substituents, and proceeds in high yields.
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