1,6-Bis(1-methyl-1<i>H</i>-tetrazol-5-ylsulfanyl)hexane

She, Jiangbo; Zhang, Guofang; Dou, Y.-L.; Fan, Xuezhong; Li, Ji‐Zhen

doi:10.1107/s1600536805042418

Cited by 16 publications

(8 citation statements)

References 4 publications

(5 reference statements)

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“…Materials and Measurements: Starting materials and solvents were of reagent grade and used without further purification. The bbbm ligand was prepared following a procedure described in literature 17. Elemental analyses were performed with a Perkin‐Elmer 2400 CHN elemental analyzer.…”

Section: Methodsmentioning

confidence: 99%

SiW₁₁Fe@MIL‐101(Cr) Composite: A Novel and Versatile Electrocatalyst

et al. 2014

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A novel composite is prepared by the incorporation of the iron‐substituted silicotungstate [SiW11FeIII(H2O)O39]5− (SiW11Fe) into the 3D structure of MIL‐101(Cr). Pyrolytic graphite electrodes are modified with SiW11Fe and the composite material SiW11Fe@MIL‐101, and the electrochemical behavior of the electrodes is studied by cyclic voltammetry. The SiW11Fe‐modified electrode shows three reduction processes: the peak at more positive potentials is assigned to FeIII→FeII and the other two peaks to WVI→WV processes. The SiW11Fe@MIL‐101‐modified electrode shows, besides the redox processes assigned to SiW11Fe, an additional peak from the MIL‐101(Cr) matrix, which corresponds to CrIII→CrII reduction. The SiW11Fe@MIL‐101‐modified electrode shows excellent tungsten‐based electrocatalytic activity towards nitrite and iodate reduction, and chromium‐based electrocatalytic properties towards ascorbic acid oxidation. It, thus, ultimately proves to be a modified electrode with multi‐electrocatalytic properties.

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Section: Methodsmentioning

confidence: 99%

SiW₁₁Fe@MIL‐101(Cr) Composite: A Novel and Versatile Electrocatalyst

et al. 2014

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“…(2011). E67, o2184 In recent years, the interesting coordination chemistry and increasingly biomedical properties of complexes derived from bis(1-methyl-1H-tetrazol) disulfide ligand have received much attention (Kim et al, 2003;She et al, 2006;Brito et al, 2007;Carballo et al, 2009;Tamilselvi & Mugesh, 2010;Wang et al, 2010). Herein we report the synthesis and crystal structure of the title compound, (I).…”

Section: Sup-1mentioning

confidence: 92%

“…For related structures, see: Kim et al (2003); Brito et al (2007); Tamilselvi & Mugesh (2010). For their use as ligands in transition-metal coordination chemistry, see: She et al (2006); Carballo et al (2009); Wang et al (2010); Aromi et al (2011).…”

Section: Related Literaturementioning

confidence: 99%

5,5′-(Disulfanediyl)bis(1-methyl-1H-tetrazole)

Cui

Liu

2011

Acta Cryst E

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In the title molecule, C4H6N8S2, two tetrazole rings linked by a disulfide bridge form a dihedral angle of 71.32 (7)° [C—S—S—C torsion angle = −80.51 (10)°]. In the crystal, strong intermolecular π–π interactions between the tetrazole rings [centroid–centroid distance = 3.285 (3) Å] link pairs of molecules into centrosymmetric dimers. Weak intermolecular C—H⋯N hydrogen bonds further link these dimers, related by translation in the [100] direction, into columns.

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“…The ligand bbbm was prepared according to the literature method [39]. The methyl orange had a k max of 506 nm in the acidic solution.…”

Section: Methodsmentioning

confidence: 99%

Synthesis, crystal structures and catalytic properties of two 1D cobalt(II) coordination polymers

Jiao

Geng

et al. 2011

Transition Met Chem

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Two new cobalt(II) coordination polymers, namely [Co 1.5 (PhCOO) 3 (bbbm) 1.5 (H 2 O)] n (1) and [Co(chdc)-(bbbm)] n (2) (bbbm = 1,1 0 -(1,4-butanediyl)bis-1H-benzimidazole, H 2 chdc = 1,4-cyclohexanedicarboxylic acid), have been synthesized and structurally characterized by single crystal X-ray diffraction. The cobalt(II) centers display different environments, with trigonal-bipyramidal and octahedral geometries in 1 and a tetrahedral geometry in 2. The 1D linear chains of complex 1 and ladder-like chains of complex 2 are bridged by bbbm in bis-monodentate coordination mode; the variation of the carboxylate co-ligand effectively tunes the resulting framework architecture. The degradation of methyl orange in a photochemical Fenton-like process using complexes 1 and 2 as catalysts was investigated.

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1,6-Bis(1-methyl-1H-tetrazol-5-ylsulfanyl)hexane

Abstract: Key indicatorsSingle-crystal X-ray study T = 293 K Mean (C-C) = 0.004 Å R factor = 0.041 wR factor = 0.119 Data-to-parameter ratio = 10.7For details of how these key indicators were automatically derived from the article, see

Cited by 16 publications

References 4 publications

SiW₁₁Fe@MIL‐101(Cr) Composite: A Novel and Versatile Electrocatalyst

SiW₁₁Fe@MIL‐101(Cr) Composite: A Novel and Versatile Electrocatalyst

5,5′-(Disulfanediyl)bis(1-methyl-1H-tetrazole)

Synthesis, crystal structures and catalytic properties of two 1D cobalt(II) coordination polymers

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1,6-Bis(1-methyl-1H-tetrazol-5-ylsulfanyl)hexane

Abstract: Key indicatorsSingle-crystal X-ray study T = 293 K Mean (C-C) = 0.004 Å R factor = 0.041 wR factor = 0.119 Data-to-parameter ratio = 10.7For details of how these key indicators were automatically derived from the article, see

Cited by 16 publications

References 4 publications

SiW11Fe@MIL‐101(Cr) Composite: A Novel and Versatile Electrocatalyst

SiW11Fe@MIL‐101(Cr) Composite: A Novel and Versatile Electrocatalyst

5,5′-(Disulfanediyl)bis(1-methyl-1H-tetrazole)

Synthesis, crystal structures and catalytic properties of two 1D cobalt(II) coordination polymers

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SiW₁₁Fe@MIL‐101(Cr) Composite: A Novel and Versatile Electrocatalyst

SiW₁₁Fe@MIL‐101(Cr) Composite: A Novel and Versatile Electrocatalyst