1994
DOI: 10.1063/1.357140
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1.54 μm wavelength emission of highly Er-doped CaF2 layers grown by molecular-beam epitaxy

Abstract: CaF2:Er layers have been grown by molecular-beam epitaxy on (100)-oriented CaF2 substrates; the Er concentration ranges from 1% to 50% (mole fraction). The 1.54 μm emission observed under excitation around 800 nm was studied by photoluminescence. Up to 35% Er concentration the integrated emission increases monotonously, quenching appearing for higher doping levels. Photoluminescence results are discussed within the framework of previous studies of Er3+ emission in the near-infrared range (830–860 nm) in order … Show more

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Cited by 22 publications
(20 citation statements)
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“…Moreover, the thermodynamical condi-tions imposed during MBE growth (low temperature and growth rate) can favorably modify the incorporation of rare-earth ions compared to bulk crystals. For example, in the case of Er-doped CaF , MBE growth has been shown to allow a significant increase in the optically active doping level [17]. Fluorides are good candidates for MBE growth as the free energies of fluoride-molecule dissociation are exceptionally high, which means that the film will have the correct stoechiometry, even at low growth temperature, unlike oxides, which are transported in the vapor as dissociated species.…”
Section: Thin-film Fabrication and Characterizationmentioning
confidence: 99%
“…Moreover, the thermodynamical condi-tions imposed during MBE growth (low temperature and growth rate) can favorably modify the incorporation of rare-earth ions compared to bulk crystals. For example, in the case of Er-doped CaF , MBE growth has been shown to allow a significant increase in the optically active doping level [17]. Fluorides are good candidates for MBE growth as the free energies of fluoride-molecule dissociation are exceptionally high, which means that the film will have the correct stoechiometry, even at low growth temperature, unlike oxides, which are transported in the vapor as dissociated species.…”
Section: Thin-film Fabrication and Characterizationmentioning
confidence: 99%
“…Although there are reports in the literature on MBE growth of waveguide films of complex ternary oxide materials such as LiNbO 3 [120] and BaTiO 3 [121], most of the work on dielectric waveguide layers to date has focused on hetero-epitaxial deposition of rare-earth doped fluoride waveguides, such as ZnF 2 , PbF 2 , [122] CaF 2 , [123] and LaF 3 [124][125][126][127]. They were grown on different dielectric and semiconductor substrates and their propagation loss was on the order of 1 dB·cm -1 [122,126,127].…”
Section: Molecular Beam Epitaxy (Mbe)mentioning
confidence: 99%
“…The low temperature luminescence spectra of Er 3ϩ doped CaF 2 layers, obtained in a back-scattering configuration, 7,9,10 have revealed the formation of Er 3ϩ centers previously identified in the bulk material. 11,12 However, as a consequence of the thermodynamic conditions imposed by the MBE technique, the proportion of complex Er 3ϩ sites relative to isolated centers has been found to be lower in the MBE layers than in the bulk for the same Er 3ϩ concentration.…”
Section: Introductionmentioning
confidence: 96%
“…In particular, Nd 3ϩ and Er 3ϩ doped CaF 2 layers have been grown on CaF 2 , GaAs, or Si substrates, [5][6][7] and recently the growth of ZnF 2 and PbF 2 -SrF 2 layers on MgF 2 and GaAs substrates, respectively, has been reported. 8 The possibility of growing good quality homoepitaxial CaF 2 layers incorporating very high concentrations of Er 3ϩ ions, up to 50 mol %, 9 has opened interesting prospects for amplification or laser action.…”
Section: Introductionmentioning
confidence: 99%