1,4-Dioxobenzene compounds of aluminium

Reversible and selective amine interactions of [Cd(μ2-N,O-p-NH2C6H4SO3)2(H2O)2]n

“…TG-IR (thermogravimetry-infrared) was carried out with a Netzsch TG-209 analyzer under flowing nitrogen. (1): sulfanilic acid (17.319 g, 0.1 mol) was dissolved in distilled water (400 mL) at 343 K and cadmium acetate dihydrate (13.317 g, 0.05 mol) was added to the above solution. After stirring for 1 h and concentration, the white precipitate was collected as…”

“…The matrix complex 1, and C 2 H 5 NH 2 and C 3 H 7 NH 2 adducts 3 and 4 were also characterized by X-ray single crystal structural analyses. Since the C 3 H 7 NH 2 adduct releases amine molecules once it is removed from the reaction vessel, the chemical formula derived from EA and TGA, which is Cd( (1) and the amine adducts (2)(3)(4)(5)(6)(7)(8). (4).…”

“…Reversible solid-gas or solid-vapor reactions of metal-organic compounds have attracted much attention recently due to their potential application as functional materials, such as chemical sensors for toxic gases or volatile organic compounds. [1][2][3][4][5] The guest up-taking capabilities of the metal-organic frameworks of interest are caused by vacant or expanded coordination sites of the metal centers, 2 also, by the accessible lattice space of the crystalline supramolecular frameworks. 4, 5 Reversible solidvapor substitution reaction occurring under mild conditions represents another unique category with only a few known examples.…”

“…4, 5 Reversible solidvapor substitution reaction occurring under mild conditions represents another unique category with only a few known examples. 1 On the other hand, metal sulfonates are a class of compounds showing interesting functional properties 6 contributed by the flexible and soft interaction between the metal atom and the sulfonate groups. Côté and Shimizu have reviewed recent progress in this field.…”

Synthesis of organoaluminum polymers with aluminum – nitrogen ring in their main-chain

“…In spite of the fact that organoaluminum compounds are highly useful, attempts to synthesize organoaluminum polymers have been limited owing to the instability of organoaluminum compounds. Although there have been a few examples of organoaluminum polymers [4,5], these were not well characterized. On the other hand, we have synthesized a wide variety of main-chain type organoboron polymers [6 -9].…”