1,4-Dioxepanes, 1,4-Oxathiepanes, and 1,4-Dithiepanes

Frauenrath, Herbert; Flock, Susanne; Murugan, Ramiah; Scriven, E. F. V.

doi:10.1016/b978-008044992-0.01212-8

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Mixed Heteroatom Seven-membered Rings1

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2013

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Cited by 1 publication

(2 citation statements)

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“…1,3-Dithianes 40 also react with alkynes 43 to form 1,4-dithiepines 44. 16 A range of oxidative techniques have been explored to convert thioethers, including those contained in a cyclic system, into the corresponding sulfoxide or sulfone. 17…”

Section: Figurementioning

confidence: 99%

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Synthesis of Biologically Active Seven-Membered-Ring Heterocycles

2013

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Seven-membered rings that contain one or more heteroatoms are interesting motifs for organic synthesis. In addition to their synthetic interest, they play an important role in industrial and pharmaceutical chemistry with generally increased central nervous system activity when flanked by aromatic rings. Herein we report a brief summary of some key methods of preparation for seven-membered-ring heterocycles and how they have been applied to the synthesis of commercially desirable products. We then detail new methods that we have developed for the synthesis of biologically active compounds containing this motif.

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Section: Figurementioning

confidence: 99%

“…Reports have primarily focused on the synthetic challenge and properties associated with this class of compounds as opposed to their applications. 15,16…”

Section: Mixed Heteroatom Seven-membered Ringsmentioning

confidence: 99%