Comprehensive Heterocyclic Chemistry II 1996
DOI: 10.1016/b978-008096518-5.00070-8
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1,3-Dithioles

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“…When submitted to iodine oxidation, the zincate complex salt , is converted into a polymeric insoluble material, (C 3 S 5 ) n , which upon heating presumably depolymerizes to the 1,3-dithiole-2,4,5-trithione 31 . This latter compound may behave as a conjugated heterodiene to afford with dienophiles the corresponding Diels−Alder cycloadducts.…”
Section: 6 Reaction Of Dmad With 13-dithiole-245-trithionementioning
confidence: 99%
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“…When submitted to iodine oxidation, the zincate complex salt , is converted into a polymeric insoluble material, (C 3 S 5 ) n , which upon heating presumably depolymerizes to the 1,3-dithiole-2,4,5-trithione 31 . This latter compound may behave as a conjugated heterodiene to afford with dienophiles the corresponding Diels−Alder cycloadducts.…”
Section: 6 Reaction Of Dmad With 13-dithiole-245-trithionementioning
confidence: 99%
“…Best results in this field have been obtained with bis(ethylenedithio)tetrathiafulvalene (BEDT-TTF) . In addition to work on electrical conductivity, applications using TTFs have progressively been extended in varied areas of modern materials. , Excellent reviews have been published regularly over the years, emphasizing either the incomparable width of possible applications of TTF-based systems (macromolecules, supramolecular systems, , donor−acceptor assemblies , ) or the extraordinary imagination developed by synthetic chemists around TTF and 1,3-dithiole frameworks.…”
Section: Introductionmentioning
confidence: 99%