1,3,5‐Triaz‐7‐Phosphatricyclo[3.3.1.1 ^3,7 ]Decane and Derivatives

Tertiary phosphine abstraction from a platinum(II) coordination complex with SeCN−: Crystal and molecular structures of SePTA and [SePTA-Me]I·CH3OH

“…PTA, O@PTA and [PTA-Me]I were prepared according to the procedure of Daigle et al [20]. S@PTA was prepared by refluxing PTA with sulphur in toluene under a nitrogen atmosphere to prevent oxidation of the PTA ligand [21].…”

Lipid-based nanoparticles containing cationic derivatives of PTA (1,3,5-triaza-7-phosphaadamantane) as innovative vehicle for Pt complexes: Production, characterization and in vitro studies

“…1A) (Daigle et al, 1974) has been recently re-discovered and widely exploited in coordination chemistry due to its ability to coordinate a wide range of metals ions via phosphorus (Daigle, 1998;Phillips et al, 2004;Bravo et al, 2010). Moreover, being highly soluble in water, stable to oxidation, non-toxic and biocompatible, PTA is a promising ligand for metal-based drugs (Casini et al, 2008).…”

Facile alternative route to cis -[PtCl 2 (PTA) 2 ] and [PtCl(PTA) 3 ]Cl (PTA = 1,3,5-triaza-7-phosphaadamantane)

“…alcohols [24][25][26] Cl [10,14,20,22]. Characterization data for 1 and 2 are given in the corresponding sections of the Supplementary materials.…”

“…1,3,5-Triaza-7-phosphaadamantane is a neutral species; it is air-stable and its aqueous solubility is usually explained by the formation of the hydrogen bonding of H 2 O with the tertiary amine nitrogens. Several researchers entitle PTA as a stable water-soluble analogues of PMe 3 [9][10][11]. Up to date, complexes of PTA with various metal centers were prepared [6][7][8], and the corresponding platinum derivatives attracted the attention of researchers due to high catalytic activity exhibited.…”