1,3,5-Tri-tert-butyl-2,4,6-triisopropyl-3,5-diaza-1-azonia-2,6-dibora- 4-borata[2.2.0]bicyclohexan, der erste Vertreter der Dewarborazine/ 1,3,5-Tri-tert-butyl-2,4,6-triisopropyl-3,5-diaza-1-azonia-2,6-dibora- 4-borata[2.2.0]bicyclohexane, the First Dewar Borazine

Paetzold, Peter; Plotho, C. Von; Schmid, Günter; Boese, Roland

doi:10.1515/znb-1984-0814

Cited by 47 publications

(12 citation statements)

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“…[40]. Similarly, hydrogen atoms have been added to the cetsup [46], cofvuo [47], bpampb [48] structures, obtained from CSD.…”

Section: Computational Detailsmentioning

confidence: 99%

“…In the second part of the research, ten organoboron molecules, i.e., cojwaa [39], cofvuo [47], sictii [58], yecvor [40], axuviy [70], zeypuo [71], bpampb [48], iditas [72], abitud [8], and notlud [73] have been investigated as molecules potentially containing double B=N bonds. Optimized r opt (B,N) bond lengths are between 1.269 Å in cojwaa and 1.455 Å for one of the BN bonds in the ring of iditas.…”

Section: The Double B=n Bondmentioning

confidence: 99%

“…In the cofvuo molecule, (iPrBNtBu) 3 , two B=N bonds are the shortest of seven B-N bonds and are expected to be of double character (see Scheme 1). The molecule has been synthetized by Paetzold et al [47] and constitutes an interesting case of six-atom cluster, consisting of three boron and three nitrogen atoms. Its optimized structure is shown in Fig.…”

Section: The Double B=n Bondmentioning

confidence: 99%

“…5 a. The trimer (iPrBNtBu) 3 is formed in a process of trimerization of the iPrBNtBu iminoborane [47]. According to Paetzold et al [47], the molecule has electronic structure resembling borazine with Dewar-type 2-center 2-electron (2c-2e) localized bonds inside the cage.…”

Section: The Double B=n Bondmentioning

confidence: 99%

“…The trimer (iPrBNtBu) 3 is formed in a process of trimerization of the iPrBNtBu iminoborane [47]. According to Paetzold et al [47], the molecule has electronic structure resembling borazine with Dewar-type 2-center 2-electron (2c-2e) localized bonds inside the cage. The experimental study [47] showed that peripheral BN bonds are short (1.364 Å, 1.384 Å) and can be characterized as double B=N bonds.…”

Section: The Double B=n Bondmentioning

confidence: 99%

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The nature of multiple boron-nitrogen bonds studied using electron localization function (ELF), electron density (AIM), and natural bond orbital (NBO) methods

2020

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Local nature of the boron-nitrogen (BN) bonding with different formal multiplicities (B≡N, B=N, B-N) have been investigated for 25 experimentally established organoboron molecules in both real and the Hilbert space, using topological analysis of electron localization function (ELF), electron density (AIM), and natural bond orbital (NBO) method. Each BN bond has been represented (ELF) by the bonding disynaptic attractor V(B,N), with the basin electron population between 5.72e and 1.83e, confirming possible existence of all the three bond types. A covalent character of bonding can be associated with the dative mechanism due to the V(B,N) bonding basin formed mainly (91-96%) by the N electron density. Similarly, the NBO method shows 2-center natural orbitals, consisting largely of the hybrids from the N atom. The AIM analysis yields the features typical for shared (H (3,−1) (r) < 0) and closed-shell (∇ 2 ρ (3,−1) (r) > 0) interactions. The delocalization indices, describing electron exchanges between B and N quantum atoms, are smaller than 1.5, even for formally very short triple B≡N bonds.

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“…[40]. Similarly, hydrogen atoms have been added to the cetsup [46], cofvuo [47], bpampb [48] structures, obtained from CSD.…”

Section: Computational Detailsmentioning

confidence: 99%

Section: The Double B=n Bondmentioning

confidence: 99%

Section: The Double B=n Bondmentioning

confidence: 99%

Section: The Double B=n Bondmentioning

confidence: 99%

Section: The Double B=n Bondmentioning

confidence: 99%

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The nature of multiple boron-nitrogen bonds studied using electron localization function (ELF), electron density (AIM), and natural bond orbital (NBO) methods

2020

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Boron–Nitrogen Compounds, Organic

Manning¹,

Griffin²

2000

Kirk-Othmer Encyclopedia of Chemical Technology

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There are four classes of B–N compounds. Amine boranes, R 3 B–NR′ 3 , have the nitrogen atom which supplies both electrons in the B–N bond; these are isoelectronic with alkanes, R 3 C–CR′ 3 . Aminoboranes, , have a covalent bond between B and N. These are isoelectronic with alkenes, . Iminoboranes, , have a two‐coordinate boron interacting with the nitrogen via a triple bond; these are isoelectronic with alkynes, . Borazines, , are cyclic compounds containing alternating tricoordinate boron and nitrogen atoms. Borazines are isoelectronic with benzene, C 6 H 6 . Amine–borane adducts have the general formula where , alkyl, etc, and , H, halogen, etc. These compounds, characterized by a coordinate covalent bond between boron and nitrogen, form a class of reducing agents having a broad spectrum of reduction potentials. Amine boranes are usually colorless, crystalline compounds which exhibit sharp melting points and thermal stability when pure. The aminoboranes are characterized by a normal covalent bond between boron and nitrogen in which an electron from each atom is shared. There exists a wide variety of aminoborane compounds; among those that have been thoroughly investigated are the monoaminoboranes X 2 BNR 2 , bisaminoboranes XB(NR 2 ) 2 , and trisaminoboranes B(NR 2 ) 3 . The substituents X and R may vary widely, but generally R is an alkyl or aryl group, or hydrogen, whereas X can represent a rather wide variety of atoms or groups. One of the more common routes for the synthesis of aminoboranes involves the aminolysis of the appropriate boron halide. Monoaminoboranes readily undergo association. The monomers are generally liquids or low melting solids, whereas the dimers and trimers are crystalline solids. Aminoboranes have been used as ligands in complexes with transition metals. The reduction of (alkylamino)haloboranes using hydride reagents can provide a convenient route to (alkylamino)boranes. Iminoboranes, SBNR, are isoelectronic with alkynes, XCCR. The polarity of the B–N bond makes iminoboranes much more reactive than the analogous SCCR species. Polar compounds add to iminoboranes, provided the addition proceeds more rapidly than oligomerization of . In an analogous fashion to the hydroboration reaction, a variety of boron‐containing substrates react with iminoboranes. The largest and most extensively studied family of boron–nitrogen compounds is that of the borazines, characterized by a six‐membered ring system containing alternating boron and nitrogen atoms. Because borazine is isoelectronic and isostructural with benzene, it has been called inorganic benzene. Borazines are liquids or crystalline solids depending on the substitution pattern. Most are sensitive to moisture and must be handled in an inert atmosphere. Borazines undergo addition reactions rather than electrophilic substitution reactions typical of benzene compounds. Borazine is slowly hydrolyzed by water at ambient or higher temperatures to boric acid. Miscellaneous reactions of borazines include photolysis and complex formation. Organic boron–nitrogen compounds have not found extensive usage, and therefore very few are manufactured on a large scale. Borazines, particularly polymeric compounds, have been extensively investigated as preceramic materials from which coatings and fibers of boron nitride can be produced upon thermolysis. B ‐Aryl and halogeno–amino borazines are reported to have seen use as fire retardants in cotton and nylon textiles. Other reported uses for borazines are as epoxy resin catalysts, polymerization inhibitors of unsaturated alcohols and esters, and catalysts for polymerization of alkenes.

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Boron‐Nitrogen Systems

Bunting¹

1990

Inorganic Reactions and Methods

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1,3,5-Tri-tert-butyl-2,4,6-triisopropyl-3,5-diaza-1-azonia-2,6-dibora- 4-borata[2.2.0]bicyclohexan, der erste Vertreter der Dewarborazine/ 1,3,5-Tri-tert-butyl-2,4,6-triisopropyl-3,5-diaza-1-azonia-2,6-dibora- 4-borata[2.2.0]bicyclohexane, the First Dewar Borazine

Cited by 47 publications

References 0 publications

The nature of multiple boron-nitrogen bonds studied using electron localization function (ELF), electron density (AIM), and natural bond orbital (NBO) methods

The nature of multiple boron-nitrogen bonds studied using electron localization function (ELF), electron density (AIM), and natural bond orbital (NBO) methods

Boron–Nitrogen Compounds, Organic

Boron‐Nitrogen Systems

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