1,2‐Bis(triazolyl)tetraphenyldigermanes: Synthesis, Structure and Properties
Kirill V. Zaitsev,
Gleb A. Veshchitsky,
Yuri F. Oprunenko
et al.
Abstract:Using the [3+2] cycloaddition reaction of [HC≡C‐GePh2‐]2 (1) and a number of RCH2N3, this work described the synthesis of a series of novel heterocyclic digermanes, bitriazoles [1,4‐C2HN3(CH2R)GePh2‐]2, 2‐12 (R = Ph, p‐Tol, p‐C6H4NMe2, p‐C6H4OMe, p‐C6H4Br, m‐C6H4NO2, 2‐Naphth, CH2‐p‐OC6H4CHO, CH2‐p‐OC6H4COOMe, CH2P(O)(OEt)2, COOEt), difficult to produce by other methods. The structural peculiarities of these compounds were studied in detail by NMR spectroscopy and by XRD analysis (for 6, 9 and 10). The propert… Show more
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