1, 1-Diaryl- and 1-Aryl-2-chloro-2-fluoroethylenes

Ando, Teiichi; Namigata, Fujio.; Kataoka, Mutsuki; Yachida, Kazutada; Funasaka, Wataru

doi:10.1246/bcsj.40.1275

Search citation statements

Order By: Relevance

Paper Sections

Select...

Methods1

Citation Types

Supporting

Mentioning

Contrasting

Year Published

1997

2015

Publication Types

Select...

Article4

Other1

Book1

Relationship

Self Cite0

Independent6

Authors

Journals

Cited by 11 publications

(1 citation statement)

References 10 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…All the products, 2a – e were identified by comparison of spectroscopic data (IR, 1 H-NMR, 13 C-NMR and 19 F-NMR) with the authentic samples as reported in [15,30,31]. The characteristic 1 H-NMR values are given below for reference: 2,2-Dichloro-2-fluoro-1-phenylethanol ( 2a ).…”

Section: Methodsmentioning

confidence: 99%

Addition of CFCl3 to Aromatic Aldehydes via in Situ Grignard Reaction

Barkakaty

Talukdar²,

Lokitz

2015

Molecules

View full text Add to dashboard Cite

Synthetic modification of trichlorofluoromethane (CFCl3) to non-volatile and useful fluorinated precursors is a cost-effective and an environmentally benign strategy for the safe consumption/destruction of the ozone depleting potential of the reagent. In this report, we present a novel method for in situ Grignard reaction using magnesium powder and CFCl3 for synthesis of dichlorofluoromethyl aromatic alcohols.

show abstract

Section: Methodsmentioning

confidence: 99%

Addition of CFCl3 to Aromatic Aldehydes via in Situ Grignard Reaction

Barkakaty

Talukdar²,

Lokitz

2015

Molecules

View full text Add to dashboard Cite

show abstract

Gryszkiewicz‐Trochimowski and McCombie Fluorination

2010

Comprehensive Organic Name Reactions and Reagents

View full text Add to dashboard Cite

This reaction is the preparation of methyl fluoroacetate by the treatment of methyl chloroacetate with potassium fluoride at high temperatures with a yield of 60% to 90%. The best conditions for this reaction have been observed to be vigorous agitation of completely dried starting materials at high temperature with potassium fluoride in large excess. This reaction has been used in the preparation of methyl fluoroacetate, ω‐fluoroalcohols, etc.

show abstract