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Yang, Ming-Chang; Sun, I‐Wen

doi:10.1023/a:1026223314259

Cited by 54 publications

(33 citation statements)

References 10 publications

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“…In the basic [BMI]Cl-AlCl 3 on Au(111), nanostrips and randomly dispersed nanoclusters have been observed for Sb, [126,151] while in the acidic [BMI]Cl-AlCl 3 on Au(111), needle-like structures or ultrathin films occur for Bi, [152] both depending on whether their UPD layers are formed. In addition, a temperature effect on the Sb OPD on a GC electrode in [EMI] [BF 4 ] has been investigated, [162] and it was found that a high temperature favors the formation of a crystalline structure.…”

Section: Semimetal (Sb Bi)mentioning

confidence: 99%

The Electrode/Ionic Liquid Interface: Electric Double Layer and Metal Electrodeposition

Wei

et al. 2010

ChemPhysChem

144

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The last decade has witnessed remarkable advances in interfacial electrochemistry in room‐temperature ionic liquids. Although the wide electrochemical window of ionic liquids is of primary concern in this new type of solvent for electrochemistry, the unusual bulk and interfacial properties brought about by the intrinsic strong interactions in the ionic liquid system also substantially influence the structure and processes at electrode/ionic liquid interfaces. Theoretical modeling and experimental characterizations have been indispensable in reaching a microscopic understanding of electrode/ionic liquid interfaces and in elucidating the physics behind new phenomena in ionic liquids. This Minireview describes the status of some aspects of interfacial electrochemistry in ionic liquids. Emphasis is placed on high‐resolution and molecular‐level characterization by scanning tunneling microscopy and vibrational spectroscopies of interfacial structures, and the initial stage of metal electrodeposition with application in surface nanostructuring.

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Section: Semimetal (Sb Bi)mentioning

confidence: 99%

The Electrode/Ionic Liquid Interface: Electric Double Layer and Metal Electrodeposition

Wei

et al. 2010

ChemPhysChem

144

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“…The electrodeposition of silver in the ionic liquid 1-butyl-3-methylimidazolium tetrafluoroborate ([BMIM]BF 4 ) was also reported. [36] It was stated that Cd, [37] Cu, [38] and Sb [39] can be electrodeposited in a basic chloride containing [EMIM]BF 4 . The electrodeposition of Pd-Au alloy in the ionic liquid [EMIM]BF 4 containing palladium(ii) and gold(i) was demonstrated.…”

Section: [Emim]bf 4 and [Bmim]bfmentioning

confidence: 99%

Electrodeposition of Metals and Semiconductors in Air‐ and Water‐Stable Ionic Liquids

2006

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In addition to their stability, the advantages of air- and water-stable ionic liquids over chloroaluminate ionic liquids, which were intensively investigated in the past, are that they are easy to dry, purify, and handle. Moreover, some of these ionic liquids have an extremely large electrochemical window of more than 5 V, and hence they give access to the electrodeposition of many metals and semiconductors, such as Ta, Ti, Si, and Ge. The results to date for the electrodeposition of metals and semiconductors in the most popular air- and water-stable ionic liquids are presented.

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“…There have been numerous investigations of the electrodeposition of tin and antimony from aqueous solutions or high-temperature molten salts reported in the literature [12][13][14][15]. However, there have been few studies on the electrochemistry of tin [5] and antimony [16,17] in ionic liquids. Hussey and Xe [5] showed that the electrodeposition of Sn on platinum in AlCl 3 -EMIC is a quasireversible process, and the diffusion coefficients of Sn(II) in acidic melt and basic melt were (5.3 ± 0.7) 9 10 -7 and (5.1 ± 0.6) 9 10 -7 cm 2 s -1 , respectively.…”

Section: Introductionmentioning

confidence: 99%

Electrodeposition of tin and antimony in 1-ethyl- 3-methylimidazolium tetrafluoroborate ionic liquid

et al. 2007

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The electrodepositions of Sn(II) and Sb (III) were studied in the [EMIm]BF 4 ionic liquid at ambient temperature. Linear sweep voltammetry (LSV) results indicated that the reductions of Sn(II) and Sb(III) on Pt electrode are electrochemically irreversible. The diffusion coefficients of Sn(II) and Sb(III) in the ionic liquid electrolyte were determined in terms of the LSV data. Tin and antimony ions form simpler Sn(II) chlorocomplex species and higher Sb(III) chlorocomplexes, respectively present in the ionic liquid electrolyte. Energy dispersive X-ray spectroscopy (EDX) analysis revealed that tin and antimony alloys can be electroplated in the ionic liquid electrolyte.

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Untitled

Cited by 54 publications

References 10 publications

The Electrode/Ionic Liquid Interface: Electric Double Layer and Metal Electrodeposition

The Electrode/Ionic Liquid Interface: Electric Double Layer and Metal Electrodeposition

Electrodeposition of Metals and Semiconductors in Air‐ and Water‐Stable Ionic Liquids

Electrodeposition of tin and antimony in 1-ethyl- 3-methylimidazolium tetrafluoroborate ionic liquid

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